Characterization of products obtained of waste polyethylene terephthalate by pyrolysis
dc.authorid | olam, mikail/0000-0002-4153-1612 | |
dc.authorid | Karaca, Huseyin/0000-0002-0543-8947 | |
dc.authorwosid | olam, mikail/CAG-0316-2022 | |
dc.authorwosid | Karaca, Huseyin/ABG-8103-2020 | |
dc.contributor.author | Olam, Mikail | |
dc.contributor.author | Karaca, Huseyin | |
dc.date.accessioned | 2024-08-04T20:51:47Z | |
dc.date.available | 2024-08-04T20:51:47Z | |
dc.date.issued | 2022 | |
dc.department | İnönü Üniversitesi | en_US |
dc.description.abstract | In this study, waste polyethylene terephthalate (wPET) was converted to liquid fuel by the pyrolysis method. It was also investigated both effects of microwave pre-treatment and catalyst (sodium borohydride) on total conversion and oil + gas yield. The reaction temperature of 375-425 degrees C and the reaction time of 30 min are sufficient for the pyrolysis of waste plastic samples in a batch reactor. In the pyrolysis of wPETs, the highest oil + gas yield of 45% was obtained under the conditions of reaction temperature of 425 degrees C and reaction time of 30 min. The highest total conversion was 62% of microwave pre-treated wPETs under catalytic conditions. It can be argued that microwave pre-treatment and NaBH4 influence the oil + gas yield in pyrolysis experiments. According to the gas chromatography-mass spectrometry (GC-MS) analysis results of the oil products, they consist of aromatic, mono and multi-ring aromatic compounds and polyaromatic compounds. Higher heating values of the solid products obtained in pyrolysis are approximately 4000-6000 cal/g. According to X-ray diffraction analysis (XRD) of the solid products, they consist largely of crystalline terephthalic acid (C8H6O4). | en_US |
dc.description.sponsorship | Inonu Universitesi [FYL2018-1176] | en_US |
dc.description.sponsorship | Inonu Universitesi, Grant/Award Number: FYL2018-1176 | en_US |
dc.identifier.doi | 10.1002/ep.13835 | |
dc.identifier.issn | 1944-7442 | |
dc.identifier.issn | 1944-7450 | |
dc.identifier.issue | 4 | en_US |
dc.identifier.scopus | 2-s2.0-85126838518 | en_US |
dc.identifier.scopusquality | Q2 | en_US |
dc.identifier.uri | https://doi.org/10.1002/ep.13835 | |
dc.identifier.uri | https://hdl.handle.net/11616/100556 | |
dc.identifier.volume | 41 | en_US |
dc.identifier.wos | WOS:000771951800001 | en_US |
dc.identifier.wosquality | Q3 | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.publisher | Wiley | en_US |
dc.relation.ispartof | Environmental Progress & Sustainable Energy | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | diesel | en_US |
dc.subject | microwave pre-treated | en_US |
dc.subject | PET | en_US |
dc.subject | pyrolysis | en_US |
dc.subject | sodium borohydride | en_US |
dc.title | Characterization of products obtained of waste polyethylene terephthalate by pyrolysis | en_US |
dc.type | Article | en_US |