Degradation of superconducting properties in MgB2 by Cu addition

dc.authoridAksan, Mehmet Ali/0000-0001-9465-0319
dc.authoridGULDESTE, Ayhan/0000-0003-4775-884X
dc.authorwosidAksan, Mehmet Ali/AAA-4187-2021
dc.authorwosidbalci, yakup/AAA-4174-2021
dc.authorwosidAksan, Mehmet Ali/AAE-8854-2021
dc.contributor.authorAksan, MA
dc.contributor.authorGüldeste, A
dc.contributor.authorBalci, Y
dc.contributor.authorYakinci, ME
dc.date.accessioned2024-08-04T20:15:13Z
dc.date.available2024-08-04T20:15:13Z
dc.date.issued2006
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe (MgB2)(2-x)CUx (x=0-0.5) superconducting system was prepared by a solid-state reaction technique. Microstructural evolution and transport properties including resistivity versus temperature up to a magnetic field of 6 T, activation energy, thermoelectric power and Fermi energy, E-F, and the corresponding velocity, V-F, values of the samples prepared were also investigated. The XRD analysis showed a multiphase formation and no detectable solution of Cu in MgB2. Two different impurity phases, MgCu2 and CuB24, have been identified and their peak intensity increased when the Cu concentration increased. The temperature dependence of the resistivity of the samples showed a metallic behavior down to T-c. But, for the Cu concentrations above 0.3 the superconducting phase transition completely disappeared. The magnetic field strongly affects the electrical properties. For x = 0.0 samples, the transition is found to be sharp, Delta T similar to 1K, but it becomes broader with increasing magnetic field and Cu concentration. The calculated values of carrier concentration, n, of the samples are showed a sharp decrease with increasing Cu content. For x = 0.0 sample the n was calculated to be 12 X 10(21) cm(-3), but for the x = 0.5 sample it decreased to 1.3 X 10(21) cm(-3). We found that the activation energy, U(B), decreased sharply with increasing magnetic field. According to thermoelectric power and Fermi energy, EF, calculations the decrease of the carrier concentration by the additions of Cu into MgB2 gives a decrease in EF and this could be attributed to a shift of the Fermi level towards the top of the sigma-hole band. (c) 2005 Elsevier Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/j.ssc.2005.11.040
dc.identifier.endpage325en_US
dc.identifier.issn0038-1098
dc.identifier.issn1879-2766
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-31444439245en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage320en_US
dc.identifier.urihttps://doi.org/10.1016/j.ssc.2005.11.040
dc.identifier.urihttps://hdl.handle.net/11616/94252
dc.identifier.volume137en_US
dc.identifier.wosWOS:000235426400009en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofSolid State Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMgB2 superconductorsen_US
dc.subjectthermoelectric poweren_US
dc.subjectelectronic transporten_US
dc.titleDegradation of superconducting properties in MgB2 by Cu additionen_US
dc.typeArticleen_US

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