Preparation of a series of Ru(II) complexes with N-heterocyclic carbene ligands for the catalytic transfer hydrogenation of aromatic ketones
Küçük Resim Yok
Tarih
2012
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Royal Soc Chemistry
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The reaction of [RuCl2(p-cymene](2) with Ag-N-heterocyclic carbene (NHC) complexes yields a series of [(p-cymene) Ru(NHC)] complexes (2a-f). All synthesised compounds were characterized by elemental analysis, NMR spectroscopy and the molecular structure of 2a was determined by X-ray crystallography. All complexes have been tested as catalysts for the transfer hydrogenation of aromatic ketones, showing excellent activity in this reaction.
Açıklama
Anahtar Kelimeler
Ruthenium Complexes, Asymmetric Hydrogenation, Stereodirecting Ligands, Efficient Catalysts, Iridium Complexes, Alpha-Arylation, Aryl Chlorides, Palladium, Hydrosilylation, Reactivity
Kaynak
Dalton Transactions
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
41
Sayı
8
