Direct C-H Bond Arylation of C2-Blocked Pyrrole with Aryl Halides Using Palladium(II)-N-Heterocyclic Carbene Catalysts

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dc.authoridKaloğlu, Murat/0000-0002-2770-5532
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authorwosidKaloğlu, Murat/AAA-3956-2021
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorKaloglu, Murat
dc.contributor.authorKaloglu, Nazan
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:44:33Z
dc.date.available2024-08-04T20:44:33Z
dc.date.issued2018
dc.departmentİnönü Üniversitesien_US
dc.description.abstractHerein we report synthesis of seven new palladium(II)-NHC complexes with the general formula [PdX2(NHC)(2)], (NHC=1,3-dialkylbenzimidazol-2-ylidene, X = Cl or Br). The structures of all the new compounds were characterized by (HNMR)-H-1, (CNMR)-C-13, FT-IR spectroscopy and elemental analysis techniques. The catalytic activities of palladium(II)-NHC complexes were tested in the direct C-H bond arylation of C2-blocked pyrrole with various aryl halides in presence of 1mol% catalyst loading at 120 degrees C for 1-16 h. Under the given conditions, palladium(II)-NHC complexes showed the good catalytic performance for the direct C-H bond arylation of C2-blocked pyrrole with aryl bromides, and with readily available and inexpensive aryl chlorides. In all cases, the C-H bond arylation regioselectively produced C5-arylated products in moderate to high yields.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey (TUBITAK-BOSPHORUS (France) [109T605]; Inonu University Research Fund (IUBAP) [2010/107, 2015/41]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey (TUBITAK-BOSPHORUS (France), Project no: 109T605) and the Inonu University Research Fund (IUBAP, Project no: 2010/107 and 2015/41).en_US
dc.identifier.doi10.1002/slct.201801045
dc.identifier.endpage5607en_US
dc.identifier.issn2365-6549
dc.identifier.issue20en_US
dc.identifier.scopus2-s2.0-85047662948en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage5600en_US
dc.identifier.urihttps://doi.org/10.1002/slct.201801045
dc.identifier.urihttps://hdl.handle.net/11616/98306
dc.identifier.volume3en_US
dc.identifier.wosWOS:000433494600016en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofChemistryselecten_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBenzimidazolium salten_US
dc.subjectDirect C-H bond arylationen_US
dc.subjectN-Heterocyclic carbeneen_US
dc.subjectPalladiumen_US
dc.subjectPyrroleen_US
dc.titleDirect C-H Bond Arylation of C2-Blocked Pyrrole with Aryl Halides Using Palladium(II)-N-Heterocyclic Carbene Catalystsen_US
dc.typeArticleen_US

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