Ruthenium(II)-NHC-catalyzed (NHC = perhydrobenzimidazol-2-ylidene) alkylation of amines using the hydrogen borrowing methodology under solvent-free conditions

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dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridkaraca, emine özge/0000-0003-2094-9742
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidkaraca, emine özge/AAH-2535-2019
dc.contributor.authorYigit, Murat
dc.contributor.authorKaraca, Emine Ozge
dc.contributor.authorYigit, Beyhan
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:45:50Z
dc.date.available2024-08-04T20:45:50Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractNew ruthenium(II) complexes with N-heterocyclic carbene ligand were synthesized by transmetalation reactions between silver(I) N-heterocyclic carbene complexes and [RuCl2(p-cymene)](2). The complexes were characterized by physicochemical and spectroscopic methods. These ruthenium complexes were applied to the N-monoalkylation of aromatic amines with a wide range of primary alcohols under solvent-free conditions using the hydrogen borrowing strategy. The catalytic reactions using all ruthenium complexes resulted in N-monoalkylated products with high selectivities using furfuryl alcohol as the alkylating agent.en_US
dc.identifier.doi10.1007/s11243-019-00313-7
dc.identifier.endpage573en_US
dc.identifier.issn0340-4285
dc.identifier.issn1572-901X
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-85063050713en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage565en_US
dc.identifier.urihttps://doi.org/10.1007/s11243-019-00313-7
dc.identifier.urihttps://hdl.handle.net/11616/98725
dc.identifier.volume44en_US
dc.identifier.wosWOS:000484918200008en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofTransition Metal Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectHeterocyclic Carbene Complexesen_US
dc.subjectCatalyzed N-Alkylationen_US
dc.subjectSecondary Alcoholsen_US
dc.subjectSaltsen_US
dc.subjectHecken_US
dc.titleRuthenium(II)-NHC-catalyzed (NHC = perhydrobenzimidazol-2-ylidene) alkylation of amines using the hydrogen borrowing methodology under solvent-free conditionsen_US
dc.typeArticleen_US

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