Synthesis and investigation of catalytic activity of phenylene - And biphenylene bridged bimetallic Palladium-PEPPSI complexes

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dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorImik, Fatma
dc.contributor.authorYasar, Sedat
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:46:00Z
dc.date.available2024-08-04T20:46:00Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA series of phenylene and biphenylene-bridged N-heterocyclic carbene (NHC) and their bimetallic NHC -Pd-PEPPSI complexes were reported and fully characterized by H-1 NMR, C-13 NMR, HRMS, FTIR, and elemental analysis. The N tags with different electronic and steric properties were used on the synthesis of bridged bimetallic NHC-Pd-PEPPSI (PEPPSI: Pyridine Enhanced Precatalyst Preparation Stabilization Initiation) complexes. The catalytic properties of the bridged bimetallic NHCePd-PEPPSI complexes were investigated in the different C-C coupling reaction such as Suzuki-Miyaura reactions of aryl bromides with arylboronic acid, the Heck coupling reactions of aryl bromide with styrene and in the Sonogashira reactions of aryl bromides with phenylacetylene. Generally, all bridged bimetallic NHCePd-PEPPSI complexes showed good catalytic activity in the CeC coupling reactions. (c) 2019 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.jorganchem.2019.06.019
dc.identifier.endpage167en_US
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.scopus2-s2.0-85067406224en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage162en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2019.06.019
dc.identifier.urihttps://hdl.handle.net/11616/98835
dc.identifier.volume896en_US
dc.identifier.wosWOS:000473598700021en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBimetallic N-heterocyclic carbene complexen_US
dc.subjectPalladiumen_US
dc.subjectC-C bond formationen_US
dc.subjectSonogashiraen_US
dc.subjectHecken_US
dc.subjectSuzukien_US
dc.titleSynthesis and investigation of catalytic activity of phenylene - And biphenylene bridged bimetallic Palladium-PEPPSI complexesen_US
dc.typeArticleen_US

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