Decomposition of rhodium and iridium complexes of tripodal phosphine derivatives studied by thermal analysis

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dc.authoridYilmaz, Veysel T./0000-0002-2849-3332
dc.authorwosidSÜLÜ, Mustafa/ABH-5282-2020
dc.authorwosidYilmaz, Veysel T./L-7238-2018
dc.contributor.authorYilmaz, VT
dc.contributor.authorSülü, M
dc.contributor.authorYazicilar, TK
dc.date.accessioned2024-08-04T20:12:18Z
dc.date.available2024-08-04T20:12:18Z
dc.date.issued2001
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThermal behaviour of five or six-coordinate rhodium and iridium complexes of two tripodal phosphines, CH3C(CH2PPh2)(3) and CH3C(CK2P(m-CF3C6H4)(2))(3), and their mixed-ligand complexes containing Cl, CO and MeCN was studied by TG, DTA and DTG in dynamic nitrogen atmosphere. The plain complexes exhibit very high thermal stability and degradation of the phosphine ligands follow a complicated process, while the first stage of the mixed-ligand complexes corresponds to removal of CO or MeCN and decomposition of the phosphine ligands occurs in the subsequent stages. All complexes undergo complete decomposition to form the respective metals as the final decomposition product. It was found that iridium complexes showed much higher thermal stability than their rhodium analogues. (C) 2001 Elsevier Science B.V. All rights reserved.en_US
dc.identifier.doi10.1016/S0040-6031(00)00717-6
dc.identifier.endpage78en_US
dc.identifier.issn0040-6031
dc.identifier.issn1872-762X
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-0035798742en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage71en_US
dc.identifier.urihttps://doi.org/10.1016/S0040-6031(00)00717-6
dc.identifier.urihttps://hdl.handle.net/11616/93351
dc.identifier.volume366en_US
dc.identifier.wosWOS:000166264700008en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofThermochimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjecttripodal phosphine complexesen_US
dc.subjectrhodium complexesen_US
dc.subjectiridium complexesen_US
dc.subjectthermal analysisen_US
dc.titleDecomposition of rhodium and iridium complexes of tripodal phosphine derivatives studied by thermal analysisen_US
dc.typeArticleen_US

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