Novel type of metal-containing polyimides for the heck and Suzuki-Miyaura cross-coupling reactions as highly active catalysts

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authoridKoytepe, Suleyman/0000-0002-4788-278X
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidKöytepe, Süleyman/AAA-4168-2021
dc.contributor.authorSeçkin, T
dc.contributor.authorKöytepe, S
dc.contributor.authorDemir, S
dc.contributor.authorÖzdemir, I
dc.contributor.authorCentinkaya, B
dc.date.accessioned2024-08-04T20:13:32Z
dc.date.available2024-08-04T20:13:32Z
dc.date.issued2003
dc.departmentİnönü Üniversitesien_US
dc.description.abstractNovel palladium (II)-containing polyimides with exceptional catalytic properties for the Heck and Suzuki-Miyaura cross-coupling reactions were prepared from Pd(II)-alpha-bis(imine) complex and the corresponding dianhyrides. The glass transition temperatures (T-g) of the polymers ranged from 169 to 241degreesC. The temperatures at which 10% weight loss occurred in air ranged from 415 to 579degreesC. Polyimides based on the palladium (II) complex were tested for catalytic activity in the Heck coupling reaction between styrene and several aryl halides and the Suzuki coupling reaction between phenylboronic acid and several aryl halides. The negative effects (e. g., expense, low reaction rates, air-sensitivity) experienced by using phosphines, particularly electron-rich phosphines, as catalysts in large scale applications is overcome by using polymer supported catalysis.en_US
dc.identifier.doi10.1023/A:1026144010812
dc.identifier.endpage235en_US
dc.identifier.issn1574-1443
dc.identifier.issn1574-1451
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-0344585366en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage223en_US
dc.identifier.urihttps://doi.org/10.1023/A:1026144010812
dc.identifier.urihttps://hdl.handle.net/11616/93681
dc.identifier.volume13en_US
dc.identifier.wosWOS:000185858000003en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectpolyimidesen_US
dc.subjectpalladium(II)-organic catalystsen_US
dc.subjectpalladium(II)-polymer complexesen_US
dc.subjectSuzuki-Miyaura cross-coupling reactionsen_US
dc.subjectHeck coupling reactionen_US
dc.subjectthermal analysisen_US
dc.titleNovel type of metal-containing polyimides for the heck and Suzuki-Miyaura cross-coupling reactions as highly active catalystsen_US
dc.typeArticleen_US

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