Systematic study on the catalytic performance of NHC-ligated silver(I) complexes

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dc.contributor.authorAkkoc, Mitat
dc.contributor.authorOnder, Belgin
dc.contributor.authorEvren, Enes
dc.contributor.authorKaraca, Emine Ozge
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2026-04-04T13:34:59Z
dc.date.available2026-04-04T13:34:59Z
dc.date.issued2026
dc.departmentİnönü Üniversitesi
dc.description.abstractThis study reports the synthesis of novel N-heterocyclic carbene (NHC) ligated silver(I) complexes, which are gaining increasing attention as versatile catalysts in organic synthesis. The structural properties of the synthesized compounds were elucidated in detail using various spectroscopic and thermal analysis techniques, including FTIR, NMR spectroscopy, and melting point determination. These analyses confirmed the successful formation of the complexes and verified that they exhibited the expected molecular structures. The low cost and unique chemical properties of silver make it an attractive alternative to other transition metals. In this context, the catalytic potential of the synthesized Ag-NHC complexes was investigated in the A3 coupling reaction, a key method for the synthesis of propargylamines. The A3 reaction is a crucial step in the formation of nitrogencontaining compounds of significant importance in pharmaceutical and natural product chemistry. Experimental results demonstrated that the Ag-NHC complexes effectively catalyzed the reaction, leading to high yields. In conclusion, this research successfully achieved the synthesis and characterization of new Ag-NHC complexes. Following the acquisition of structural analysis data, their catalytic activity in the A3 coupling reaction was successfully investigated.
dc.description.sponsorshipScientific Research Projects Unit of Inonue University [FDP-2025-4235]
dc.description.sponsorshipThis study was supported by the Scientific Research Projects Unit of Inonue University (Project No: FDP-2025-4235).
dc.identifier.doi10.1016/j.jorganchem.2026.124053
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.scopus2-s2.0-105029248047
dc.identifier.scopusqualityQ2
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2026.124053
dc.identifier.urihttps://hdl.handle.net/11616/109520
dc.identifier.volume1049
dc.identifier.wosWOS:001686938000001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier Science Sa
dc.relation.ispartofJournal of Organometallic Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250329
dc.subjectA3 Coupling
dc.subjectNHC
dc.subjectPropargylamines
dc.subjectSilver
dc.titleSystematic study on the catalytic performance of NHC-ligated silver(I) complexes
dc.typeArticle

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