Synthesis, characterization, electrochemical behaviors and applications in the Suzuki-Miyaura cross-coupling reactions of N2S2O2 thio Schiff base ligand and its Cu(II), Co(III), Ni(II), Pd(II) complexes and their usage in the fabrication of organic-inorganic hybrid devices

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dc.authoridyilmaz, ismail/0000-0002-5046-7456
dc.authoridOcak, Yusuf Selim/0000-0001-8754-1720
dc.authoridPaşa, Salih/0000-0002-4792-8821
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridDüşünceli, Serpil Demir/0000-0001-8765-4039
dc.authorwosidDemir, Serpil/AAI-1740-2019
dc.authorwosidyilmaz, ismail/N-6592-2014
dc.authorwosidOcak, Yusuf Selim/AAH-7230-2019
dc.authorwosidPaşa, Salih/AAC-9404-2019
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidDüşünceli, Serpil Demir/AAA-7160-2021
dc.contributor.authorTemel, Hamdi
dc.contributor.authorPasa, Salih
dc.contributor.authorOcak, Yusuf Selim
dc.contributor.authorYilmaz, Ismail
dc.contributor.authorDemir, Serpil
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:35:42Z
dc.date.available2024-08-04T20:35:42Z
dc.date.issued2012
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe thio Schiff base ligand N,N'-bis(o-hydroxy-1-naphtaldehydene)-1,2-bis(o-amino phenilthio)ethane (L) was synthesized by the condensation of o-hydroxy-1-naphthaldehyde and 1,2-bis(2-amino thiophenol)ethane. The reactions of the ligand with different transition metal(II) salts under reflux system condition afforded a series of metal complexes such as Cu(II), Co(III), Ni(II) and Pd(II). Ligand and its complexes were characterized by a combination of elemental analysis, UV-vis spectroscopy, FT-IR, H-1 NMR, MS and TGA/DTA. The electrochemical properties of L and [Cu(L)] were investigated using cyclic voltammetry (CV) in the solutions of dimethyl sulfoxide (DMSO). The catalytic property of thio Schiff base ligand with Suzuki cross-coupling reactions were also determined with different substituted aryl halides in the presence of aryl boronic acid and Pd(AcO)(2) as catalyst. In addition, the fabrication of organic-inorganic hybrid devices using L and its Co(III), Ni(II) and Pd(II) complexes and their electrical properties have been reported. (C) 2011 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.synthmet.2011.10.018
dc.identifier.endpage2775en_US
dc.identifier.issn0379-6779
dc.identifier.issue23-24en_US
dc.identifier.scopus2-s2.0-84855896178en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage2765en_US
dc.identifier.urihttps://doi.org/10.1016/j.synthmet.2011.10.018
dc.identifier.urihttps://hdl.handle.net/11616/95536
dc.identifier.volume161en_US
dc.identifier.wosWOS:000300653700048en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofSynthetic Metalsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject2-Amino Thiophenolen_US
dc.subjectSuzuki couplingen_US
dc.subjectCyclic voltammetryen_US
dc.subjectOrganic-inorganic heterojunctionen_US
dc.titleSynthesis, characterization, electrochemical behaviors and applications in the Suzuki-Miyaura cross-coupling reactions of N2S2O2 thio Schiff base ligand and its Cu(II), Co(III), Ni(II), Pd(II) complexes and their usage in the fabrication of organic-inorganic hybrid devicesen_US
dc.typeArticleen_US

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