Synthesis and Self-assembling Properties of 2,2':6',2aEuro3-Terpyridine-Based Carbon Nanotube Coordination Polymers
Küçük Resim Yok
Tarih
2013
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
A novel metallo-supramolecular polytopic ligand was synthesized from the attachment reaction involving an amino group-functionalized multi-wall carbon nanotube and 4-chloro-2,2':6',2aEuro(3)-terpyridine used for the preparation of metallo-supramolecular polymers with Co(II) or Ni(II) ions. Different colors were observed depending on either the ligands or the metal ions in this type of supramolecular assembly. The created supramolecular polymers were characterized by means of structure, morphology, and stimuli-responsive performance employing scanning electron microscopy, amperometric techniques, UV-Vis and Fourier transform infrared spectroscopy. UV-Vis spectroscopy and cyclic voltammetry studies confirmed that both the optical and electrochemical properties of metallo-supramolecular materials are affected by the substituent at the pyridine periphery.
Açıklama
Anahtar Kelimeler
Supramolecular polymers, MWCNT, Coordination chemistry, Terpyridine ligands
Kaynak
Journal of Inorganic and Organometallic Polymers and Materials
WoS Q Değeri
Q3
Scopus Q Değeri
Q2
Cilt
23
Sayı
5
