Synthesis and catalytic properties of arene complexes of ruthenium(II) prepared from Si, Zr, Ti and Al alkoxides by the sol-gel process
Küçük Resim Yok
Tarih
1998
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Royal Soc Chemistry
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Methods of synthesizing materials for catalysis were developed by synthesizing eta-arene complexes of ruthenium(II) coordinated to vinylpyridine that was followed by sol-gel polymerization with 3-methacryloxypropyltriethoxysilane. To enforce sufficient catalytic properties, a series of hybrid materials from Si, Zr, Ti and Al alkoxides were prepared by co-condensation. The hydrolysis and polycondensation of materials were performed at different experimental conditions. The monomeric compounds were identified and catalytic activities were tested for cyclization of (Z)-3-methylpent-2-en-4-yn-1-ol to 2,3-dimethylfuran.
Açıklama
Anahtar Kelimeler
Metal-Complexes, Hydrosilanes, Rhodium
Kaynak
Journal of Materials Chemistry
WoS Q Değeri
Q1
Scopus Q Değeri
N/A
Cilt
8
Sayı
8
