Synthesis of palladium complexes derived from imidazolidin-2-ylidene ligands and used for catalytic amination reactions

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dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridkaraca, emine özge/0000-0003-2094-9742
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridyasar, sedat/0000-0001-7285-2761
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidkaraca, emine özge/AAH-2535-2019
dc.authorwosidSahin, Onur/KGM-3910-2024
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorKaraca, Emine Ozge
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorSahin, Onur
dc.contributor.authorBuyukgungor, Orhan
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:41:51Z
dc.date.available2024-08-04T20:41:51Z
dc.date.issued2016
dc.departmentİnönü Üniversitesien_US
dc.description.abstractN-Aryl amination and the Buchwald-Hartwig reaction are of great synthetic and industrial interest and scientists accept their usefulness and versatility for obtaining arylamines. In this study Ag-N-heterocyclic carbene complexes were used as trans-metallation reagents for the synthesis of Pd-N-heterocyclic carbene complexes. The new Pd-N-heterocyclic carbene complexes were characterized using elemental analysis and H-1 NMR, C-13 NMR and infrared spectroscopies. The crystal structure of one, namely dichlorobis[1,3-bis(2-methylbenzyl)imidazolidin-2-yliden]palladium(II), is presented. The activity of the Pd(II) complexes in the coupling reaction of anilines or amines with bromobenzene was investigated. These complexes exhibited high catalytic activities in the direct synthesis of triarylamines and secondary amines in a single step. Copyright (C) 2016 John Wiley & Sons, Ltd.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK-BOSPHORUS (France) [109T605]; Inonu University [IUBAP: 2014/32-Gudumlu]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK-BOSPHORUS (France) [109T605] and Inonu University Research Fund (IUBAP: 2014/32-Gudumlu).en_US
dc.identifier.doi10.1002/aoc.3541
dc.identifier.endpage1055en_US
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue12en_US
dc.identifier.scopus2-s2.0-84976874885en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1050en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.3541
dc.identifier.urihttps://hdl.handle.net/11616/97391
dc.identifier.volume30en_US
dc.identifier.wosWOS:000388267500011en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectimidazolidin-2-ylideneen_US
dc.subjectpalladiumen_US
dc.subjectaminationen_US
dc.titleSynthesis of palladium complexes derived from imidazolidin-2-ylidene ligands and used for catalytic amination reactionsen_US
dc.typeArticleen_US

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