The ruthenium and iridium coordination chemistry of the tripodal ligand CH3C{CH2P(m-CF3-C6H4)2}3

Basit Öğe Kaydı
dc.authorwosidSÜLÜ, Mustafa/ABH-5282-2020
dc.contributor.authorSülü, M
dc.contributor.authorVenanzi, LM
dc.date.accessioned2024-08-04T20:30:47Z
dc.date.available2024-08-04T20:30:47Z
dc.date.issued1999
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe ruthenium(II) complexes [Ru(CF3CO2)(2)(CF(3)triphos)], [Ru-2(mu-Cl)(3)(CF(3)triphos)(2)]Cl, [RuH(CH3CN)(2)(CF(3)triphos)](CF3SO3) and [Ru(CH3CN)(3)(CF(3)triphos)](CF3SO3)(2) (CF(3)triphos = CH3C{CH2P(m-CF3C6H4)(2)}(3)) were prepared and characterized. The iridium complexes [Ir(COD)(CF(3)triphos)](+), [IrCl(CO)(CF(3)triphos)], [Ir(CO)(2)(CF(3)triphos)](+), [IrCl3(CF(3)triphos)] and [IrCl3-n(MeCN)(n)(CF(3)triphos)](CF3SO3)(n) (n = 1, 2 and 3) were also prepared and characterized. The coordination chemistries of these two elements with CF(3)triphos and with the unsubstituted ligand CH3C{CH2P(C6H5)(2)}(3) (Htriphos) are compared. It is shown that, relative to Htriphos, CF(3)triphos (a) stabilizes the iridium(I) relative to the iridium(III) oxidation state and (b) its cationic complexes are stronger Lewis acids. (C) 1999 Elsevier Science S.A. All rights reserved.en_US
dc.identifier.doi10.1016/S0020-1693(99)00236-4
dc.identifier.endpage79en_US
dc.identifier.issn0020-1693
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-4243258290en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage70en_US
dc.identifier.urihttps://doi.org/10.1016/S0020-1693(99)00236-4
dc.identifier.urihttps://hdl.handle.net/11616/94510
dc.identifier.volume293en_US
dc.identifier.wosWOS:000082763900009en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectruthenium complexesen_US
dc.subjectiridium complexesen_US
dc.subjecttripodal ligandsen_US
dc.titleThe ruthenium and iridium coordination chemistry of the tripodal ligand CH3C{CH2P(m-CF3-C6H4)2}3en_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu