Catalytic activity of Ru/tetrahydropyrimidinium salts system for transfer hydrogenation reactions

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dc.authoridkaraca, emine özge/0000-0003-2094-9742
dc.authoridArslan, Hakan/0000-0003-0046-9442
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridyasar, sedat/0000-0001-7285-2761
dc.authorwosidkaraca, emine özge/AAH-2535-2019
dc.authorwosidArslan, Hakan/B-1081-2008
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.contributor.authorKaraca, Emine Ozge
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorArslan, Hakan
dc.contributor.authorVanDerveer, Don
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:43:57Z
dc.date.available2024-08-04T20:43:57Z
dc.date.issued2015
dc.departmentİnönü Üniversitesien_US
dc.description.abstractNew 1,3-dialkyltetrahydropyrimidinium salts as NHC precursors have been synthesized and characterized. The in situ prepared three-component 1,3-dialkyltetrahydropyrimidinium salts/[RuCl2(p-cymene)](2) and KOH catalyzes quantitatively the transfer hydrogenation of ketones under mild reaction conditions in 2-propanol. Also, the molecular structure of 1,3-bis(2-methylbenzyl)-3,4,5,6-tetrahydropyrimidinium was determined using single-crystal X-ray diffraction. Ions of the title compound are linked by CH...Cl and OH...Cl hydrogen bonding interactions. The NCN bond angle (124.3(2)degrees) and CN bond lengths (1.316(3) and 1.314(3) angstrom) confirm the existence of strong resonance in this part of the molecule. Copyright (c) 2015 John Wiley & Sons, Ltd.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK [TBAG (107 T098)]; Inonu University Research Fund [IUBAP: 2013/51]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK (TBAG (107 T098)) and Inonu University Research Fund (IUBAP: 2013/51).en_US
dc.identifier.doi10.1002/aoc.3322
dc.identifier.endpage480en_US
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-85027941279en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage475en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.3322
dc.identifier.urihttps://hdl.handle.net/11616/97939
dc.identifier.volume29en_US
dc.identifier.wosWOS:000356708100010en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-Blackwellen_US
dc.relation.ispartofApplied Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectrutheniumen_US
dc.subjecttetrahydropyrimidin-2-ylideneen_US
dc.subjectN-heterocyclic carbineen_US
dc.subjecttransfer hydrogenationen_US
dc.subjectketoneen_US
dc.titleCatalytic activity of Ru/tetrahydropyrimidinium salts system for transfer hydrogenation reactionsen_US
dc.typeArticleen_US

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