Synthesis of ruthenium(II) N-heterocyclic carbene complexes and their catalytic activities in transfer hydrogenation of ketones
Küçük Resim Yok
Tarih
2012
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Three RuCI 2(? 6-arene, ? 1-carbene) and two RuCI 2(NHC)(arene) complexes have been prepared by the reaction of bis(1,3-dialkylperhydrobenzimidazol-2-ylidene) (1) and bis(1,3-dialkyl-4-methylzimidazolin-2-ylidene) (3) with [RuCI 2(arene)] 2 in toluene and characterized by elemental analysis, 1H NMR, 13C NMR and IR spectroscopy. The catalytic activities of these complexes were examined in the transfer hydrogenation of aromatic ketones using 2-propanol as hydrogen source. © Springer Science+Business Media B.V. 2012.
Açıklama
Anahtar Kelimeler
2-propanol, Aromatic ketones, Carbenes, Hydrogen sources, N-heterocyclic carbene complex, Transfer hydrogenations, Catalyst activity, Hydrogen, Hydrogenation, Ketones, Organic compounds, Ruthenium, Toluene, Ruthenium compounds
Kaynak
Transition Metal Chemistry
WoS Q Değeri
Scopus Q Değeri
Q2
Cilt
37
Sayı
3
