Catalytic activities in direct arylation of novel palladium N-heterocyclic carbene complexes

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dc.authoridAkkoc, Senem/0000-0002-1260-9425
dc.authorwosidAkkoç, Senem/AAN-1478-2021
dc.authorwosidGök, Yetkin/AAA-5669-2021
dc.contributor.authorAkkoc, Senem
dc.contributor.authorGok, Yetkin
dc.date.accessioned2024-08-04T20:39:59Z
dc.date.available2024-08-04T20:39:59Z
dc.date.issued2014
dc.departmentİnönü Üniversitesien_US
dc.description.abstractEight novel palladium N-heterocyclic carbene (Pd-NHC) complexes were synthesized by the reaction of chloro 1,3-dialkylbenzimidazolin-2-ylidene silver(I) complexes with bis(benzonitrile)palladium(II) chloride in dichloromethane. These eight Pd-NHC complexes are as follows: bis[1-phenyl-3-(2,4,6-trimethylbenzyl)benzimidazol-2-ylidene]dichloropalladium(II), bis[1-phenyl-3-(2,3,5,6-tetramethylbenzyl)benzimidazol-2-ylidene]dichloropalladium(II), bis[1-phenyl-3-(2,3,4,5,6-pentamethylbenzyl)benzimidazol-2-ylidene]dichloropalladium(II), bis[1-phenyl-3-(3,4,5-trimethoxybenzyl)benzimidazol-2-ylidene]dichloropalladium(II), bis[1-(2-diethylaminoethyl)-3-(3-methylbenzyl)benzimidazol-2-ylidene]dichloropalladium(II), bis[1-(2-diethylaminoethyl)-3-(2,3,5,6-tetramethylbenzyl)benzimidazol-2-ylidene]dichloropalladium(II),bis[1-(2-morpholinoethyl)-3-naphthalenomethylbenzimidazol-2-ylidene]dichloropalladium(II) and bis[1-(2-morpholinoethyl)-3-(2-methylbenzyl)benzimidazol-2-ylidene]dichloropalladium(II). Also, these synthesized complexes were fully characterized using Fourier transform infrared, H-1 NMR and C-13 NMR spectroscopic methods and elemental analysis techniques. These synthesized novel Pd-NHC complexes were tested as catalysts in the direct arylation of 2-n-butylthiophene, 2-n-butylfuran and 2-isopropylthiazole with various aryl bromides at 130 degrees C for 1 h. The complexes showed very good catalytic activities in these reactions. Copyright (c) 2014 John Wiley & Sons, Ltd.en_US
dc.description.sponsorshipInonu University Research Fund [IUBAP 2011/130]en_US
dc.description.sponsorshipThis work was financially supported by Inonu University Research Fund (IUBAP 2011/130).en_US
dc.identifier.doi10.1002/aoc.3220
dc.identifier.endpage860en_US
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue12en_US
dc.identifier.scopus2-s2.0-84918793634en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage854en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.3220
dc.identifier.urihttps://hdl.handle.net/11616/96635
dc.identifier.volume28en_US
dc.identifier.wosWOS:000345349900001en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectpalladium complexen_US
dc.subjectdirect arylationen_US
dc.subjectaryl bromideen_US
dc.titleCatalytic activities in direct arylation of novel palladium N-heterocyclic carbene complexesen_US
dc.typeArticleen_US

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