Synthesis and catalytic properties of N-functionalized carbene complexes of rhodium(I) and ruthenium(II)

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorCetinkaya, B
dc.contributor.authorOzdemir, I
dc.contributor.authorDixneuf, PH
dc.date.accessioned2024-08-04T20:11:57Z
dc.date.available2024-08-04T20:11:57Z
dc.date.issued1997
dc.departmentİnönü Üniversitesien_US
dc.description.abstractImidazolidin-2-ylidene derivatives of rhodium(I) and ruthenium(II), having 2-methoxyethyl substituent on the N-atom, [Rh(L)Cl(PPh3)(2)], [Rh(L)Cl(COD)] or [Ru(L)Cl-2(arene)] (L-1 = CN(Me)CH2CH2NCH2CH2OMe and L-2 = CN(CH2CH2OMe)CH2CH2NCH2CH2OMe) have been prepared by treatment of [RhCl(PPh3)(3)], [RhCl(COD)](2) or [RuCl2(arene)](2) with the N-functionalized electron-rich olefins L-1 = L-1 or L-2 = L-2. All of the new carbene rhodium(I) or ruthenium(II) complexes have proved to be effective catalysts for the cyclopropanation reactions of diazoalkane derivatives with styrene and the rhodium(I) precursors lead to the highest catalytic activity.en_US
dc.identifier.doi10.1016/S0022-328X(96)06927-6
dc.identifier.endpage158en_US
dc.identifier.issn0022-328X
dc.identifier.issue1-2en_US
dc.identifier.scopus2-s2.0-0031589115en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage153en_US
dc.identifier.urihttps://doi.org/10.1016/S0022-328X(96)06927-6
dc.identifier.urihttps://hdl.handle.net/11616/93099
dc.identifier.volume534en_US
dc.identifier.wosWOS:A1997XH60100018en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectcarbeneen_US
dc.subjectimidazoleen_US
dc.subjectrutheniumen_US
dc.subjectcatalysisen_US
dc.subjectrhodiumen_US
dc.subjectcyclopropanationen_US
dc.titleSynthesis and catalytic properties of N-functionalized carbene complexes of rhodium(I) and ruthenium(II)en_US
dc.typeArticleen_US

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