2-methyl-1,4-benzodioxan-substituted bis(NHC)PdX2 complexes: Synthesis, characterization and the catalytic activity in the direct arylation reaction of some 2-alkyl-heterocyclic compounds

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dc.authoridAktaş, Aydın/0000-0001-8496-6782;
dc.authorwosidAktaş, Aydın/J-6194-2019
dc.authorwosidGök, Yetkin/AAA-5669-2021
dc.contributor.authorGok, Yetkin
dc.contributor.authorAktas, Aydin
dc.contributor.authorSari, Yakup
dc.contributor.authorErdogan, Hulya
dc.date.accessioned2024-08-04T20:45:41Z
dc.date.available2024-08-04T20:45:41Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractAlmost in all fields of chemistry, the C-C cross-coupling reactions such as the direct arylation reaction have attracted much attention and have advanced quickly in recent years due to the importance of environment-friendly properties. This study contains the synthesis of the 2-methyl-1,4-benzodioxan-substituted bis(NHC)PdX2 complexes and their catalytic activity in direct arylation reaction. The bis(NHC)PdX2 complexes have been prepared from the 2-methyl-1,4-benzodioxan-substituted Ag(I)NHC complexes via transmetallation method. The bis(NHC)PdX2 complexes have been characterized using H-1 NMR, C-13 NMR, FT-IR spectroscopy and elemental analysis techniques. The bis(NHC)PdX2 complexes have been examined as catalysts in the direct arylation reactions with 2-n-butylfuran, 2-n-butylthiophene and 2-isopropylthiazole, and have demonstrated excellent activity in these reactions.en_US
dc.description.sponsorshipInonu University Research Fund [IUBAP 2011/21]en_US
dc.description.sponsorshipThis work was financially supported by Inonu University Research Fund (IUBAP 2011/21) and the authors acknowledge Inonu University Scientific and Technology Center for the elemental analyses of the compounds.en_US
dc.identifier.doi10.1007/s13738-018-1512-y
dc.identifier.endpage433en_US
dc.identifier.issn1735-207X
dc.identifier.issn1735-2428
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-85060330229en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage423en_US
dc.identifier.urihttps://doi.org/10.1007/s13738-018-1512-y
dc.identifier.urihttps://hdl.handle.net/11616/98619
dc.identifier.volume16en_US
dc.identifier.wosWOS:000458026600022en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of The Iranian Chemical Societyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-Heterocyclic carbenesen_US
dc.subjectDirect arylationen_US
dc.subjectButylfuranen_US
dc.subjectButylthiopheneen_US
dc.subject2-Isopropylthiazoleen_US
dc.title2-methyl-1,4-benzodioxan-substituted bis(NHC)PdX2 complexes: Synthesis, characterization and the catalytic activity in the direct arylation reaction of some 2-alkyl-heterocyclic compoundsen_US
dc.typeArticleen_US

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