Magnetic Cu/Co nanoparticles supported on nitrogen-doped porous carbon derived from Cu/Co@aZIF: Investigation of catalytic activity and structural properties
Küçük Resim Yok
Tarih
2023
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Wiley
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
By calcining copper-doped amorphous zeolitic imidazolate framework (Cu/Co@aZIF), a novel magnetic nanoporous carbon composite (Cu/Co@NPC) material was produced, characterized by different spectroscopic techniques, and used for the first time as an efficient catalyst for the azide-alkyne cycloaddition (AAC) reaction and the reduction reaction of nitrophenol (RRN) under air in water. With this catalyst, the AAC and RRN reactions were conducted in aqueous solutions, and good to excellent yields of related products were synthesized in a short reaction time. The potential of the magnetic Cu/Co@NPC nanocatalyst for targeting RRN and AAC reactions was uncovered by studying specific substrates for RRN and AAC reactions. The Cu/Co@NPC magnetic nanocatalyst is recyclable at least five times, with just a drop of 6% and 22% in catalytic efficiency in RRN and AAC, respectively.
Açıklama
Anahtar Kelimeler
AAC reaction, copper, MOF, nitrophenol, porous carbon
Kaynak
Applied Organometallic Chemistry
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
37
Sayı
3
