2-Hydroxyethyl-Substituted Pd-PEPPSI Complexes: Synthesis, Characterization and the Catalytic Activity in the Suzuki-Miyaura Reaction for Aryl Chlorides in Aqueous Media

Basit Öğe Kaydı
dc.authoridAktaş, Aydın/0000-0001-8496-6782
dc.authoridAygün, Muhittin/0000-0001-9670-9062;
dc.authorwosidAktaş, Aydın/J-6194-2019
dc.authorwosidAygün, Muhittin/P-3605-2019
dc.authorwosidGök, Yetkin/AAA-5669-2021
dc.authorwosidBarut Celepci, Duygu/M-6189-2017
dc.contributor.authorAktas, Aydin
dc.contributor.authorCelepci, Duygu Barut
dc.contributor.authorGok, Yetkin
dc.contributor.authorAygun, Muhittin
dc.date.accessioned2024-08-04T20:45:25Z
dc.date.available2024-08-04T20:45:25Z
dc.date.issued2018
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn recent years, PEPPSI (Pyridine-Enhanced Precatalyst Preparation Stabilization and Initiation) complexes have attracted attention in organometallic chemistry. This study contains the synthesis of the 2-hydroxyethyl-substituted Pd-PEPPSI complexes and their catalytic activity in the Suzuki-Miyaura reaction aryl chlorides in aqueous media. The Pd-PEPPSI complexes have been prepared from the 2- hydroxyethyl-substituted N-heterocyclic carbene (NHC) precursors, palladium chloride and 3-chloropyridine. The Pd-PEPPSI complexes have been characterized by using (HNMR)-H-1, (CNMR)-C-13, FTIR spectroscopy and elemental analysis techniques. The Pd-PEPPSI complexes have been examined as catalysts in the Suzuki-Miyaura reactions in aqueous media with arylboronic acid derivatives. Also, they have demonstrated excellent activity in these reactions. Molecular and crystal structure of one of the 2-hydroxyethyl substituted Pd-PEPPSI complex was determined by single crystal X-ray diffraction method. X-ray studies show that the molecular structure adopts a slightly distorted square-planar geometry with the palladium (II) center.en_US
dc.description.sponsorshipDokuz Eylul University for the use of the Oxford Rigaku Xcalibur Eos Diffractometer [2010.KB.FEN.13]en_US
dc.description.sponsorshipThe authors acknowledge Inonu University Scientific and Technology Center for the elemental analyses of the compounds. The authors acknowledge Dokuz Eylul University for the use of the Oxford Rigaku Xcalibur Eos Diffractometer (purchased under University Research Grant No: 2010.KB.FEN.13).en_US
dc.identifier.doi10.1002/slct.201802046
dc.identifier.endpage9980en_US
dc.identifier.issn2365-6549
dc.identifier.issue35en_US
dc.identifier.scopus2-s2.0-85053614228en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage9974en_US
dc.identifier.urihttps://doi.org/10.1002/slct.201802046
dc.identifier.urihttps://hdl.handle.net/11616/98473
dc.identifier.volume3en_US
dc.identifier.wosWOS:000445178600002en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofChemistryselecten_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-Heterocyclic carbenesen_US
dc.subjectPd-PEPPSI complexesen_US
dc.subjectPhenylboronic aciden_US
dc.subjectSuzuki-Miyaura reactionen_US
dc.subjectX-ray diffractionen_US
dc.title2-Hydroxyethyl-Substituted Pd-PEPPSI Complexes: Synthesis, Characterization and the Catalytic Activity in the Suzuki-Miyaura Reaction for Aryl Chlorides in Aqueous Mediaen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu