Half-sandwich ruthenium-carbene catalysts: Synthesis, characterization, and catalytic application in the N-alkylation of amines with alcohols

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dc.authoridKaloğlu, Murat/0000-0002-2770-5532
dc.authorwosidKaloğlu, Murat/AAA-3956-2021
dc.contributor.authorKaloglu, Murat
dc.date.accessioned2024-08-04T20:46:47Z
dc.date.available2024-08-04T20:46:47Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this study, the synthesis and characterization of new half-sandwich ruthenium complexes containing oxygen functionalised N-aryl and N-alkyl benzimidazol-2-ylidene ligands have been reported. All ruthenium complexes were tested as catalysts for a wide range of substrates in the N-alkylation of secondary cyclic amines such as pyrrolidine and piperidine, and 4-methylaniline which was a primary aromatic amine with alcohols by hydrogen-borrowing process. The catalytic reactions were performed with 1 mol% catalyst loading at 120 degrees C, 16 h under solvent-free conditions. All ruthenium complexes showed excellent catalytic activity, and N-alkylated products were obtained selectively.en_US
dc.identifier.doi10.1016/j.ica.2019.119163
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-85072639878en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2019.119163
dc.identifier.urihttps://hdl.handle.net/11616/98965
dc.identifier.volume498en_US
dc.identifier.wosWOS:000501778900019en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-Heterocyclic carbeneen_US
dc.subjectRutheniumen_US
dc.subjectN-Alkylation of aminesen_US
dc.subjectHydrogen-borrowing processen_US
dc.titleHalf-sandwich ruthenium-carbene catalysts: Synthesis, characterization, and catalytic application in the N-alkylation of amines with alcoholsen_US
dc.typeArticleen_US

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