Palladium(II) N-heterocyclic carbene complexes as catalysts for the direct arylation of pyrrole derivatives with aryl chlorides

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dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorYigit, Beyhan
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorYigit, Murat
dc.contributor.authorDagdeviren, Zeynep
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:43:10Z
dc.date.available2024-08-04T20:43:10Z
dc.date.issued2017
dc.departmentİnönü Üniversitesien_US
dc.description.abstractSilver(I) N-heterocyclic carbene complexes were synthesized in good yields by the reactions of 1,3-dialkylperhydrobenzimidazolyum salts with silver(I) oxide and used as transmetallation reagents for the synthesis of palladium(II) N-heterocyclic carbene complexes. All of the complexes were characterized using elemental analysis, H-1 NMR and C-13 NMR spectroscopy. The catalytic activity of Pd(II)-NHC complexes in the direct arylation of pyrrole derivatives was investigated. These Pd(II)-NHC complexes showed the good catalytic performance for the direct arylation of pyrrole derivatives with readily available and inexpensive aryl chlorides. The arylation reactions regioselectively produced C2- or C5-arylation products in moderate to good yields by using 1 mol% of the palladium complex. (C) 2017 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipAdiyaman University Research Fund [FEF-MAP/2015-0004]; Inonu University Research Fund [IUBAP: 2015/41-Gudumlu]en_US
dc.description.sponsorshipWe thank the Adiyaman University Research Fund (FEF-MAP/2015-0004) and Inonu University Research Fund (IUBAP: 2015/41-Gudumlu) for financial support of this work.en_US
dc.identifier.doi10.1016/j.ica.2017.05.047
dc.identifier.endpage49en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-85020010714en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage44en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2017.05.047
dc.identifier.urihttps://hdl.handle.net/11616/97832
dc.identifier.volume465en_US
dc.identifier.wosWOS:000404701200006en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectC-H Arylationen_US
dc.subjectBenzimidazolium Saltsen_US
dc.subjectDirect C5-Arylationen_US
dc.subjectFunctionalizationen_US
dc.subjectImidazolesen_US
dc.subjectThiopheneen_US
dc.subjectBromidesen_US
dc.subjectIodidesen_US
dc.subjectHecken_US
dc.subjectSubstituenten_US
dc.titlePalladium(II) N-heterocyclic carbene complexes as catalysts for the direct arylation of pyrrole derivatives with aryl chloridesen_US
dc.typeArticleen_US

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