Synthesis, electrochemical, biological and catalytical studies of half-sandwich Ru(II)-NSHC complexes bearing benzothiazol-2-ylidene

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dc.authorscopusid59132916000
dc.authorscopusid16052784700
dc.authorscopusid57200289982
dc.authorscopusid57223038605
dc.authorscopusid7005334931
dc.authorscopusid57196914953
dc.authorscopusid8398877200
dc.contributor.authorTuncer H.
dc.contributor.authorKılınçarslan R.
dc.contributor.authorKarci H.
dc.contributor.authorDündar M.
dc.contributor.authorÖzdemir İ.
dc.contributor.authorKoç A.
dc.contributor.authorÖzdemir N.
dc.date.accessioned2024-08-04T19:59:08Z
dc.date.available2024-08-04T19:59:08Z
dc.date.issued2024
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe half-sandwich ruthenium(II)-NSHC complexes (2a-l) bearing benzothiazol-2-ylidene were synthesized by in situ deprotonation of N-substituted benzothiazolium salts (1a-l) with Ag2O and of [(p-cymene)Cl2Ru]2, in dichloromethane under mild conditions. However, 1m and 1n under the same conditions gave N-coordinated Ru(II) complex (3). The structures of the compounds were elucidated by NMR, FT-IR, UV–Vis, HR-MS spectroscopic methods and elemental analysis. In addition, the structures of 2k and 3 were studied by X-ray crystallography. The electrochemical properties of the complexes were investigated. Ru(II)-NSHC complexes have been used as catalysts in the transfer hydrogenation of carbonyls to secondary alcohols in the presence i-PrOH/KOH. Additionally, the effects of structural differences arising from different alkyl groups on the nitrogen atom in the benzothiazole skeleton in Ru(II)-NSHC complexes on anticancer, antifungal and antimicrobial activity were also examined. © 2024 Elsevier B.V.en_US
dc.description.sponsorship2021FEBE034en_US
dc.description.sponsorshipWe would like to thank Pamukkale University Scientific Research Projects Commission (Project No: 2021FEBE034) for providing financial support to this study.en_US
dc.identifier.doi10.1016/j.molstruc.2024.139424
dc.identifier.issn0022-2860
dc.identifier.scopus2-s2.0-85199436326en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2024.139424
dc.identifier.urihttps://hdl.handle.net/11616/90423
dc.identifier.volume1318en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier B.V.en_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAnticanceren_US
dc.subjectBenzothiazol-2-ylideneen_US
dc.subjectBiological activityen_US
dc.subjectHalf-sandwich Ru(II) complexen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectTransfer hydrogenationen_US
dc.titleSynthesis, electrochemical, biological and catalytical studies of half-sandwich Ru(II)-NSHC complexes bearing benzothiazol-2-ylideneen_US
dc.typeArticleen_US

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