Synthesis, characterization, and microwave-promoted catalytic activity of novel benzimidazole salts bearing silicon-containing substituents in Heck-Mizoroki and Suzuki-Miyaura cross-coupling reactions under aerobic conditions

Basit Öğe Kaydı
dc.contributor.authorKüçükbay, Hasan
dc.contributor.authorÜlkü, Nihat Şireci
dc.contributor.authorYılmaz, Ülkü
dc.contributor.authorDeniz, Selma
dc.contributor.authorAkkurt, Mehmet
dc.contributor.authorBaktır, Zeliha
dc.contributor.authorBüyükgüngör, Orhan
dc.date.accessioned2020-06-27T15:56:43Z
dc.date.available2020-06-27T15:56:43Z
dc.date.issued2012
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA number of benzimidazole derivatives (1-8) were synthesized and the catalytic activity of these compounds in a catalytic system including Pd(OAc) 2 and K2 CO3 in DMF-H2 O was evaluated in Heck-Mizoroki and Suzuki-Miyaura cross-coupling reactions of aryl iodides, bromides, and chlorides with styrene and arylboronic acids under microwave irradiation and aerobic conditions. The yields of both the Heck-Mizoroki and the Suzuki-Miyaura cross coupling reactions with aryl iodides and aryl bromides were nearly quantitative. The synthesized 1-substituted benzimidazole (1) and benzimidazole salts (2-8) were identified by 1 Hand 13 C-NMR and IR spectroscopic methods, and micro analysis. The molecular structure of 7 was also determined by X-ray crystallography. Key Words: Benzimidazole salt, N-heterocyclic carbene, palladium catalysis, Heck-Mizoroki couplingen_US
dc.identifier.citationHasan K. Nihat Ş. Ülkü Y. Selma D. Mehmet A. Zeliha B. Orhan B. (2012). Synthesis, characterization, and microwave-promoted catalytic activity of novel benzimidazole salts bearing silicon-containing substituents in Heck-Mizoroki and Suzuki-Miyaura cross-coupling reactions under aerobic conditions, Turkish Journal of Chemistry, İnönü Üniversitesi, Malatya.en_US
dc.identifier.endpage207en_US
dc.identifier.issn1300-0527
dc.identifier.issn1303-6130
dc.identifier.issue2en_US
dc.identifier.startpage201en_US
dc.identifier.trdizinid128512en_US
dc.identifier.urihttps://hdl.handle.net/11616/16121
dc.identifier.urihttps://search.trdizin.gov.tr/yayin/detay/128512
dc.identifier.volume36en_US
dc.identifier.wosWOS:000302661200001en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakTR-Dizinen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isotren_US
dc.publisherTurkish Journal of Chemistryen_US
dc.relation.ispartofTurkish Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectMühendisliken_US
dc.subjectKimyaen_US
dc.titleSynthesis, characterization, and microwave-promoted catalytic activity of novel benzimidazole salts bearing silicon-containing substituents in Heck-Mizoroki and Suzuki-Miyaura cross-coupling reactions under aerobic conditionsen_US
dc.typeArticleen_US

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim
İsim:
Makale Dosyası.pdf
Boyut:
710.53 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Makale Dosyası
İndir
Lisans paketi
Listeleniyor 1 - 1 / 1
Küçük Resim Yok
İsim:
license.txt
Boyut:
1.71 KB
Biçim:
Item-specific license agreed upon to submission
Açıklama:
İndir

Koleksiyon

TR-Dizin İndeksli Yayınlar Koleksiyonu
WoS İndeksli Yayınlar Koleksiyonu