Direct arylation (hetero-coupling) of heteroarenes via unsymmetrical palladium-PEPPSI-NHC type complexes

Basit Öğe Kaydı
dc.authoridTahir, Muhammad Nawaz/0000-0002-6815-9806
dc.authoridAshfaq, Muhammad/0000-0001-6663-8777
dc.authoridKarci, Huseyin/0000-0002-5709-1623
dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authorwosidTahir, Muhammad Nawaz/HPB-5726-2023
dc.authorwosidAshfaq, Muhammad/ABG-2654-2021
dc.authorwosidKarci, Huseyin/AAC-3985-2022
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.contributor.authorNawaz, Zahid
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorZafar, Muhammad Naveed
dc.contributor.authorTahir, Muhammad Nawaz
dc.contributor.authorAshfaq, Muhammad
dc.contributor.authorKarci, Huseyin
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:50:32Z
dc.date.available2024-08-04T20:50:32Z
dc.date.issued2021
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe growing interest of industry in the field of bi(hetero)arenes compounds, motivated us to synthesize these compounds via homogeneous catalytic route by using Pd PEPPSI-type complexes through direct arylation. In this work, the five new Pd PEPPSI-type complexes bearing NHC spectator ligands were synthesized and characterized by a bunch of spectroscopic techniques. Further confirmations of structural details were provided by a single crystal X-ray diffraction study of one pro-ligand and one complex. All these newly synthesized Pd-carbene complexes were found significantly active as catalysts toward direct arylation of five members heterocyclic compounds such as n-propylthaizole, 2-acetylfurane and 2-acetylthiophene with aryl bromides derivatives. These catalysts give significantly good results within two hours with just 1 mol % catalyst loading.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey (TuBITAK) [2216]; Inodnu University Research Fund [Iu-BAP: FBG-2019-1594]en_US
dc.description.sponsorshipThe authors gratefully acknowledged his deep appreciation to the Technological and Scientific Research Council of Turkey (TuBITAK) for his Ph.D. research funding (2216 Research Fellowship Programme) . This study was supported by Inodnu University Research Fund (Iu-BAP: FBG-2019-1594) .en_US
dc.identifier.doi10.1016/j.poly.2021.115412
dc.identifier.issn0277-5387
dc.identifier.issn1873-3719
dc.identifier.scopus2-s2.0-85112364797en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2021.115412
dc.identifier.urihttps://hdl.handle.net/11616/100117
dc.identifier.volume208en_US
dc.identifier.wosWOS:000696897500009en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBenzimidazolium Chloridesen_US
dc.subjectPalladium-PEPPSIen_US
dc.subjectHomogeneous catalysten_US
dc.subjectC-H bond activationen_US
dc.subjectDirect arylation reactionen_US
dc.titleDirect arylation (hetero-coupling) of heteroarenes via unsymmetrical palladium-PEPPSI-NHC type complexesen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu