Microwave-Assisted Synthesis of Novel Perimidinium Salts as N-Heterocyclic Carbene Precursors: Involvement in Palladium-Catalyzed Cross-Coupling Reactions
Küçük Resim Yok
Tarih
2015
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In the current study, five novel perimidinium chlorides were synthesized in good yields by reaction of 1-(3-methylbenzyl)perimidine with five different alkyl chlorides under microwave irradiation in 30 minutes. Synthesized compounds were characterized by IR, H-1, C-13 NMR spectroscopic methods and elemental analyses. Performance of in situ formed catalytic system which consist of the perimidinium salts and Pd(OAc)(2) was investigated for Heck and Suzuki reactions in aqueous media, and desired products were obtained in good yields.
Açıklama
Anahtar Kelimeler
carbenes, palladium, perimidine, catalysis, Heck reaction, microwave irradiation, Suzuki reaction
Kaynak
Chemistry of Heterocyclic Compounds
WoS Q Değeri
Q4
Scopus Q Değeri
Q3
Cilt
51
Sayı
6
