Synthesis of Phenanthroline-Functionalized Phosphazene Based Metallosupramolecular Polymers and Their Stimuli-Responsive Properties

Basit Öğe Kaydı
dc.authoridSEZER, Selda/0000-0002-3136-1250
dc.authoridSEÇKİN, Turgay/0000-0001-8483-7366
dc.authoridKoytepe, Suleyman/0000-0002-4788-278X
dc.authorwosidSEZER, Selda/GQZ-6467-2022
dc.authorwosidSEÇKİN, Turgay/ABG-7537-2020
dc.authorwosidKöytepe, Süleyman/AAA-4168-2021
dc.contributor.authorSeckin, Turgay
dc.contributor.authorSezer, Selda
dc.contributor.authorKoytepe, Suleyman
dc.date.accessioned2024-08-04T20:45:22Z
dc.date.available2024-08-04T20:45:22Z
dc.date.issued2018
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA series of phenanthroline-functionalized phosphazene based metallo-supramolecular polymers (PFP-MSP) was synthesised using a two-step reaction strategy. In first step, three phenanthroline unit containing monomer (PFP-M) was prepared from 5,6-dihydroxy-1,10-phenanthroline and hexachlorocyclotriphosphazene by condensation reaction. Then, this PFP-M was reacted with different metal ion salts (Co, Ni, Cu, Fe, Eu, La, Tb, Lu ions) and resulting for the metallo-supramolecular polymers bearing phosphazene structure. Obtained PFP-MSPs were characterized by spectroscopic analysis, elemental analysis, Scanning electron microscopy measurement and SEM-energy dispersive X-ray spectrometry techniques. Stimuli responsible and opto-electronic properties of synthesized PFP-MSPs were also studied for different external stimulating factors, such as electrochemical or the addition of competitive complexing ligands by UV-Vis spectroscopy and electroanalytic techniques. As a result, prepared PFP-MSPs are good alternatives for photochromic, electrochromic, opto-electronic and smart material applications.en_US
dc.description.sponsorshipTuBTAK-The Scientific and Technological Research Council of Turkey [115R023]en_US
dc.description.sponsorshipAuthors would like to thank TuBTAK-The Scientific and Technological Research Council of Turkey for the financial support with the Project Number 115R023.en_US
dc.identifier.doi10.1007/s10904-018-0938-0
dc.identifier.endpage2834en_US
dc.identifier.issn1574-1443
dc.identifier.issn1574-1451
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-85051494410en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage2825en_US
dc.identifier.urihttps://doi.org/10.1007/s10904-018-0938-0
dc.identifier.urihttps://hdl.handle.net/11616/98428
dc.identifier.volume28en_US
dc.identifier.wosWOS:000449330700065en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSupramolecular chemistryen_US
dc.subjectMetal coordinated polymersen_US
dc.subjectMetallo-supramolecular polymersen_US
dc.subjectCyclotriphosphazeneen_US
dc.subjectPhenanthroline ligandsen_US
dc.titleSynthesis of Phenanthroline-Functionalized Phosphazene Based Metallosupramolecular Polymers and Their Stimuli-Responsive Propertiesen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu