Synthesis of novel rhodium-xylyl linked N-heterocyclic carbene complexes as hydrosilylation catalysts

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dc.authoridDüşünceli, Serpil Demir/0000-0001-8765-4039
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authorwosidDemir, Serpil/AAI-1740-2019
dc.authorwosidDüşünceli, Serpil Demir/AAA-7160-2021
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidSahin, Onur/KGM-3910-2024
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorDemir, Serpil
dc.contributor.authorSahin, Onur
dc.contributor.authorBuyukgungor, Orhan
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2024-08-04T20:30:58Z
dc.date.available2024-08-04T20:30:58Z
dc.date.issued2008
dc.departmentİnönü Üniversitesien_US
dc.description.abstractReaction of ortho-xylylbis(N-2,4,6-trimethylbenzylimidazolinium);xylylbis(N-butylimidazolinium) and para-xylylbis(N-2,4,6-trimethylbenzylimidazolinium); xylylbis(N-butylimidazolinium) salts with KOBut and [RhCl(COD)](2) yields ortho- and para-xylylbis{(N-alkylimidazolidin-2-ylidene)chloro(eta(4)-1,5-cyclooctadiene) rho dium(I)} complexes (2a-d). All compounds synthesized were characterized by elemental analysis and NMR spectroscopy, and the molecular structures of the 2a and 2d were determined by X-ray crystallography. Triethylsilane reacts with acetophenone derivatives in the presence of catalytic amount of the new rhodium(I)-carbene complexes (2a-d), to give the corresponding silylethers in good yields (83-99%). Copyright (C) 2008 John Wiley & Sons, Ltd.en_US
dc.identifier.doi10.1002/aoc.1353
dc.identifier.endpage66en_US
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-51449087989en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage59en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.1353
dc.identifier.urihttps://hdl.handle.net/11616/94646
dc.identifier.volume22en_US
dc.identifier.wosWOS:000253691100013en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectxylylbis(imidazolinium) saltsen_US
dc.subjecthydrosilylationen_US
dc.subjectrhodiumen_US
dc.titleSynthesis of novel rhodium-xylyl linked N-heterocyclic carbene complexes as hydrosilylation catalystsen_US
dc.typeArticleen_US

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