AMINOLYSIS OF P-TRICHLORO-N-DICHLOROPHOSPHORYLMONOPHOSPHAZENE AND THE CRYSTAL-STRUCTURE OF 1-(DICHLOROPHOSPHINYL)-2-CHLORO-2,2-BIS(DIISOPROPYLAMINO)PHOSPHAZINE

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.authoridErcan, filiz/0000-0002-3533-0726
dc.authorwosidHokelek, Tuncer/G-6068-2013
dc.authorwosidERCAN, FİLİZ/G-6063-2013
dc.authorwosidHokelek, Tuncer/JCE-0691-2023
dc.authorwosidErcan, filiz/AAG-7962-2019
dc.contributor.authorKILIC, Z
dc.contributor.authorGUNDUZ, N
dc.contributor.authorYILDIZ, M
dc.contributor.authorKILIC, A
dc.contributor.authorMOR, S
dc.contributor.authorERCAN, F
dc.contributor.authorHOKELEK, T
dc.date.accessioned2024-08-04T20:42:41Z
dc.date.available2024-08-04T20:42:41Z
dc.date.issued1994
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe reactions of Cl3P=N-P(O)Cl-2 (1) with primary and secondary amines have been studied. The following monophosphazenes, (RRN)(3)P=N-P(O)(NRR)(2), and bis(phosphinoyl)amines, [(RRN)(2)P(O)]2NH were isolated: NRR = NHCH(2)Ph, NEt(2), NH(CH2)(2)CH3 groups for monophosphazenes, and NEt(2), NH(CH2)(2)CH3 for phosphinoyl amines. The unexpected geminal phosphazene, Cl(RRN)(2)P=N-P(O)Cl-2, {RRN = N[CH(CH3)(2)](2)}, was also obtained in moderate yield. The spectral data (IR, H-1, C-13, and P-31 NMR, and MS) are presented. The structure of 1-(dichlorophosphinyl)-2-chloro-2,2-bis(diisopropylamino) phosphazene (5) was determined by X-ray crystallography. The basicities of these and related compounds in nonaqueous nitrobenzene solution were obtained by potentiometric titration.en_US
dc.identifier.doi10.1002/hc.520050406
dc.identifier.endpage357en_US
dc.identifier.issn1042-7163
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-84987471868en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage349en_US
dc.identifier.urihttps://doi.org/10.1002/hc.520050406
dc.identifier.urihttps://hdl.handle.net/11616/97500
dc.identifier.volume5en_US
dc.identifier.wosWOS:A1994PV63000005en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherJohn Wiley & Sons Incen_US
dc.relation.ispartofHeteroatom Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPhosphorus-Nitrogen-Compoundsen_US
dc.subjectCl2p(O).N=Pcl3en_US
dc.subjectCl3p=N-P(O)Cl2en_US
dc.subjectConformationen_US
dc.subjectDerivativesen_US
dc.titleAMINOLYSIS OF P-TRICHLORO-N-DICHLOROPHOSPHORYLMONOPHOSPHAZENE AND THE CRYSTAL-STRUCTURE OF 1-(DICHLOROPHOSPHINYL)-2-CHLORO-2,2-BIS(DIISOPROPYLAMINO)PHOSPHAZINEen_US
dc.typeArticleen_US

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