Palladium(II)-NHC complexes containing benzimidazole ligand as a catalyst for C-N bond formation

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridDüşünceli, Serpil Demir/0000-0001-8765-4039
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidDüşünceli, Serpil Demir/AAA-7160-2021
dc.authorwosidDemir, Serpil/AAI-1740-2019
dc.contributor.authorDogan, Oznur
dc.contributor.authorDemir, Serpil
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2024-08-04T20:32:42Z
dc.date.available2024-08-04T20:32:42Z
dc.date.issued2011
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe reaction of 2-(2-bromoethyl)-1,3-dioxane with 1-alkylbenzimidazole derivatives results in the formation of the new benzimidazoliumsalts (1). The reaction of Pd(OAc)(2) with1,3-dialkylbenzimidazoliumsalts(1a-c) yields palladium N-heterocyclic carbene (NHC) complexes (2a-c). All synthesized compounds were characterized by (HNMR)-H-1, (CNMR)-C-13, IR and elemental analysis techniques which support the proposed structures. As catalysts, these new palladium complexes offer a simple and efficient methodology for the synthesis of triarylamines and secondary amines from anilines and amines and in a single step with potassium tertiary butoxide as a base. Copyright (C) 2010 John Wiley & Sons, Ltd.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK-CNRS (France) [TBAG-U/181 (106T716)]; Inonu University [IU BAP: 2009/10]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK-CNRS (France) [TBAG-U/181 (106T716)] and Inonu University Research Fund (IU BAP: 2009/10).en_US
dc.identifier.doi10.1002/aoc.1731
dc.identifier.endpage167en_US
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-79951490615en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage163en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.1731
dc.identifier.urihttps://hdl.handle.net/11616/95254
dc.identifier.volume25en_US
dc.identifier.wosWOS:000287164100001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectbenzimidazolium salten_US
dc.subjectpalladium catalysisen_US
dc.subjectaminationen_US
dc.subjectN-heterocyclic carbeneen_US
dc.titlePalladium(II)-NHC complexes containing benzimidazole ligand as a catalyst for C-N bond formationen_US
dc.typeArticleen_US

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