Synthesis, crystal structures and catalytic activities of palladium complexes with coumarin-functionalised N-heterocyclic carbene ligands

Basit Öğe Kaydı
dc.authoridÖzdemir, Namık/0000-0003-3371-9874
dc.authorwosidÖzdemir, Namık/J-6434-2015
dc.contributor.authorAkpunar, Ceren
dc.contributor.authorOzdemir, Namik
dc.contributor.authorKaratas, Mert Olgun
dc.contributor.authorAlici, Bulent
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:50:23Z
dc.date.available2024-08-04T20:50:23Z
dc.date.issued2021
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this contribution, we synthesized five new coumarin-functionalised PEPPSI type Pd-NHC complexes in order to examine their catalyst properties. The complexes were synthesized by the reaction of PdCl2 and corresponding benzimidazolium chloride in pyridine in the presence of excess amount of K2CO3. The structures of complexes were fully characterised using NMR and IR spectroscopy, elemental analyses and X-ray diffraction analyses. Crystal structures of four complexes revealed that they have slightly distorted square-planar geometry. Catalytic activities of complexes were tested in Suzuki-Miyaura reaction of phenylboronic acid and aryl bromide derivatives in H2O-DMF solvent system.en_US
dc.description.sponsorshipScientific Research Projects Unit of Ondokuz Mays University [PYO.FEN.1906.19.001]en_US
dc.description.sponsorshipThis study was supported by Scientific Research Projects Unit of Ondokuz Mays University (Project No: PYO.FEN.1906.19.001) .en_US
dc.identifier.doi10.1016/j.inoche.2021.108755
dc.identifier.issn1387-7003
dc.identifier.issn1879-0259
dc.identifier.scopus2-s2.0-85108986205en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.inoche.2021.108755
dc.identifier.urihttps://hdl.handle.net/11616/100016
dc.identifier.volume131en_US
dc.identifier.wosWOS:000684594900004en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofInorganic Chemistry Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectPalladiumen_US
dc.subjectCoumarinen_US
dc.subjectCatalysisen_US
dc.subjectSuzuki-Miyaura reactionen_US
dc.titleSynthesis, crystal structures and catalytic activities of palladium complexes with coumarin-functionalised N-heterocyclic carbene ligandsen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu