Dichloride [1-(2,4,6-trimethylbenzyl)-3-(biphenyl-2-ylmethyl)-imidazolidin-2-ylidine (?6-hexamethylbenzene)]ruthenium
Küçük Resim Yok
Tarih
2006
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Tubitak Scientific & Technological Research Council Turkey
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The single crystal X-ray structure of the imidazolidin ruthenium complex, C38H46N2Cl2Ru, was determined. The complex is an orthorhombic space group Pbca with a = 17.3586(32) angstrom, b = 14.4447(27) angstrom, c = 27.4325(52) angstrom, and V = 6878.466(4) angstrom(3) with Z = 8 for D-calc = 1.357 g/cm(3). It exhibits the expected 3-legged piano stool geometry. There is one coordination bond of the ruthenium atom with the electrons of the eta(6)-hexamethylbenzene, 2 symmetrical Ru-Cl bonds, and one Ru-C bond involving the imidazole ring. The coordination around the ruthenium atom is 4-fold, which in this is case is pseudo-tetrahedral.
Açıklama
Anahtar Kelimeler
arenes, carbenes, imidazole, ruthenium complex, X-ray structure
Kaynak
Turkish Journal of Chemistry
WoS Q Değeri
Q3
Scopus Q Değeri
Cilt
30
Sayı
5
