Dichloride [1-(2,4,6-trimethylbenzyl)-3-(biphenyl-2-ylmethyl)-imidazolidin-2-ylidine (?6-hexamethylbenzene)]ruthenium

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dc.authoridArslan, Hakan/0000-0003-0046-9442
dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authorwosidArslan, Hakan/B-1081-2008
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorArslan, Hakan
dc.contributor.authorVan Derveer, Donald
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorYasar, Sedat
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2024-08-04T20:57:41Z
dc.date.available2024-08-04T20:57:41Z
dc.date.issued2006
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe single crystal X-ray structure of the imidazolidin ruthenium complex, C38H46N2Cl2Ru, was determined. The complex is an orthorhombic space group Pbca with a = 17.3586(32) angstrom, b = 14.4447(27) angstrom, c = 27.4325(52) angstrom, and V = 6878.466(4) angstrom(3) with Z = 8 for D-calc = 1.357 g/cm(3). It exhibits the expected 3-legged piano stool geometry. There is one coordination bond of the ruthenium atom with the electrons of the eta(6)-hexamethylbenzene, 2 symmetrical Ru-Cl bonds, and one Ru-C bond involving the imidazole ring. The coordination around the ruthenium atom is 4-fold, which in this is case is pseudo-tetrahedral.en_US
dc.identifier.endpage541en_US
dc.identifier.issn1300-0527
dc.identifier.issue5en_US
dc.identifier.startpage535en_US
dc.identifier.urihttps://hdl.handle.net/11616/102835
dc.identifier.volume30en_US
dc.identifier.wosWOS:000243366000001en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.language.isoenen_US
dc.publisherTubitak Scientific & Technological Research Council Turkeyen_US
dc.relation.ispartofTurkish Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectarenesen_US
dc.subjectcarbenesen_US
dc.subjectimidazoleen_US
dc.subjectruthenium complexen_US
dc.subjectX-ray structureen_US
dc.titleDichloride [1-(2,4,6-trimethylbenzyl)-3-(biphenyl-2-ylmethyl)-imidazolidin-2-ylidine (?6-hexamethylbenzene)]rutheniumen_US
dc.typeArticleen_US

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