Preparation and Catalytic Properties of a Ru(II) Coordinated Polyimide Supported by a Ligand Containing Terpyridine Units

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dc.authoridSEÇKİN, Turgay/0000-0001-8483-7366
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridKoytepe, Suleyman/0000-0002-4788-278X
dc.authorwosidSEÇKİN, Turgay/ABG-7537-2020
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidKöytepe, Süleyman/AAA-4168-2021
dc.contributor.authorSeckin, Turgay
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorKoytepe, Sueleyman
dc.contributor.authorGurbuz, Nevin
dc.date.accessioned2024-08-04T20:31:15Z
dc.date.available2024-08-04T20:31:15Z
dc.date.issued2009
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe synthesis of terpyridine-based polyimide catalysis for hydrosilylation reaction is outlined in this work. 5,5''-Bis(bromomethyl)-2,2':6',2''-terpyridine was polymerized with the corresponding diimide derivatives of dianhyrides to give polyimides utilizing the terpyridine unit in the main chain. The synthesis of polyimides containing Ru(II) complexes in the side chain is described. Condensation polymerization is used to synthesize the macromolecular backbone and, as a result, the Ru(II) complex was attached via coordination chemistry. The material design emphasizes the relationship between the molecular structure and supramolecular organization of these polymers. It demonstrates that terpyridyl complexes remain a versatile functionality for constructing supramolecular assemblies. The terpyridine unit may enhance the electron carrier mobility of the polymers, while the incorporation of ruthenium complexes into a conjugated polymer significantly changes the catalytic properties of the resulting polymers. The prepared polyimide-supported catalyst provides superior catalytic activity (70-79%), selectivity and stability in the hydrosilylation of acetophenone. The catalyst can be easily isolated from the reaction product, which benefits recycling. The catalysts were reused for four experiments.en_US
dc.identifier.doi10.1007/s10904-009-9262-z
dc.identifier.endpage151en_US
dc.identifier.issn1574-1443
dc.identifier.issn1574-1451
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-67349224348en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage143en_US
dc.identifier.urihttps://doi.org/10.1007/s10904-009-9262-z
dc.identifier.urihttps://hdl.handle.net/11616/94822
dc.identifier.volume19en_US
dc.identifier.wosWOS:000265398400003en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectMetal complexesen_US
dc.subjectPolyimideen_US
dc.subjectHeterogeneous catalysisen_US
dc.subjectHydosilylationen_US
dc.titlePreparation and Catalytic Properties of a Ru(II) Coordinated Polyimide Supported by a Ligand Containing Terpyridine Unitsen_US
dc.typeArticleen_US

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