Ruthenium(II) complexes bearing N-heterocyclic carbene ligands with wingtip groups and their catalytic activity in the transfer hydrogenation of ketones

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dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridEvren, Enes/0000-0002-7571-410X
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidBarut Celepci, Duygu/M-6189-2017
dc.contributor.authorYigit, Beyhan
dc.contributor.authorIsik, Yilmaz
dc.contributor.authorCelepci, Duygu Barut
dc.contributor.authorEvren, Enes
dc.contributor.authorYigit, Murat
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:46:48Z
dc.date.available2024-08-04T20:46:48Z
dc.date.issued2020
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA series of new silver(I) complexes bearing N-heterocyclic carbene (NHC) ligands with wingtip groups were synthesized by the reaction of 1,3-dialkylimidazolinium salts with silver(I) oxide in dichloromethane. The silver complexes were used as carbene-transfer agents to synthesize ruthenium(II) complexes with the general formula [RuCl2(NHC)(eta(6)-p-cymene)]. All the synthesized complexes were characterized by elemental analysis, FT-IR, H-1 NMR and C-13 NMR spectroscopy, and the molecular and crystal structure of 3d was determined by single-crystal X-ray diffraction. These ruthenium complexes were tested as catalysts in the transfer hydrogenation of ketones using (PrOH)-Pr-i as a hydrogen source. All compounds tested showed good catalytic activity in these reactions.en_US
dc.description.sponsorshipAdiyaman University Research Fund [FEFYL/2017-0004]; [2010.KB.FEN.13]en_US
dc.description.sponsorshipWe thank the Adiyaman University Research Fund (FEFYL/2017-0004) for financial support of this work. The authors acknowledge Dokuz Eyliil University for the use of the Rigaku Oxford Xcalibur Eos Diffractometer (purchased under University Research Grant No: 2010.KB.FEN.13).en_US
dc.identifier.doi10.1016/j.ica.2019.119199
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-85073209816en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2019.119199
dc.identifier.urihttps://hdl.handle.net/11616/98971
dc.identifier.volume499en_US
dc.identifier.wosWOS:000498751600008en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-Heterocyclic carbeneen_US
dc.subjectRuthenium complexesen_US
dc.subjectSilver complexesen_US
dc.subjectTransfer hydrogenationen_US
dc.titleRuthenium(II) complexes bearing N-heterocyclic carbene ligands with wingtip groups and their catalytic activity in the transfer hydrogenation of ketonesen_US
dc.typeArticleen_US

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