Synthesis and structural characterization of N,N-spiro cyclotriphosphazene derivatives with one stereogenic center

Basit Öğe Kaydı
dc.authoridBegeç, Saliha/0000-0001-5331-6736
dc.authorwosidBegeç, Saliha/AAA-9708-2021
dc.contributor.authorBegec, Saliha
dc.date.accessioned2024-08-04T20:52:09Z
dc.date.available2024-08-04T20:52:09Z
dc.date.issued2023
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this study, N,N-spiro cyclotriphosphazene derivatives (1a-4a) with one stereogenic center were synthesized in two steps. Firstly; mono substituted phosphazene compounds [N3P3Cl5NHC6H5 (1), N3P3Cl5OC5H4N (2), N3P3Cl5OC6H2-Me-2,4,6 (3), N3P3Cl5OC6H2-Bu-t-2-Me-4 (4)] were prepared. Secondly, these compounds (1-4) were allowed to react with symmetrical difunctional reagent N,N '-diisopropylpropane-1,3-diamine to obtain cyclotriphosphazenes having one stereogenic center. The reaction of N3P3Cl5XAr (1-4) with N,N '-diisopropylpropane-1,3-diamine was carried out in dichloromethane. Four new N,N-spiro phosphazene compounds (1a-4a) which have one stereogenic center were obtained from these reactions. The structures of these compounds were characterized by H-1, C-13 and P-31 NMR spectrometry and elemental analyses.en_US
dc.identifier.doi10.1080/10426507.2022.2099859
dc.identifier.endpage20en_US
dc.identifier.issn1042-6507
dc.identifier.issn1563-5325
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-85134309882en_US
dc.identifier.scopusqualityQ4en_US
dc.identifier.startpage15en_US
dc.identifier.urihttps://doi.org/10.1080/10426507.2022.2099859
dc.identifier.urihttps://hdl.handle.net/11616/100789
dc.identifier.volume198en_US
dc.identifier.wosWOS:000827578500001en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Ltden_US
dc.relation.ispartofPhosphorus Sulfur and Silicon and The Related Elementsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPhosphazenesen_US
dc.subjectspiro phosphazenesen_US
dc.subjectN,N '-diisopropylpropane-1,3-diamineen_US
dc.subjecthexachlorocyclotriphosphazatrieneen_US
dc.subjectstereogenic centeren_US
dc.subjectN,N-spiroen_US
dc.titleSynthesis and structural characterization of N,N-spiro cyclotriphosphazene derivatives with one stereogenic centeren_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu