Synthesis, crystal structures, spectral FT-IR, NMR and UV-Vis investigations and Hirshfeld surface analysis of two new 2-hydroxyethyl-substituted N-heterocyclic carbene precursors

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dc.authoridAktaş, Aydın/0000-0001-8496-6782
dc.authorwosidGök, Yetkin/AAA-5669-2021
dc.authorwosidBarut Celepci, Duygu/M-6189-2017
dc.authorwosidAktaş, Aydın/J-6194-2019
dc.contributor.authorAktas, Aydin
dc.contributor.authorCelepci, Duygu Barut
dc.contributor.authorGok, Yetkin
dc.date.accessioned2024-08-04T20:45:56Z
dc.date.available2024-08-04T20:45:56Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThis study discusses the synthesis of two new 2-hydroxyethyl substituted N-heterocyclic carbene (NHC) precursors. The NHC precursors were prepared from 1-(alkyl/aryl)benzimidazole and alkyl halides. They were characterized using H-1 NMR, C-13 NMR, FT-IR, UV-Vis spectroscopy, and elemental analysis techniques. Molecular and crystal structures of 1 and 2 were determined using the single-crystal X-ray diffraction method. Crystal structure of the compounds features NHC precursors and chloride anions. Additionally in 2, the asymmetric unit has a water molecule, which forms a tetrameric chloride-hydrate assembly with the chloride anion. The chloride anions play an important role in the stabilization of crystal structures to form a two-dimensional supramolecular architecture. The 3D Hirshfeld surface and the associated 2D fingerprint plots were also drawn to gain insights into the behavior of the interactions in the compounds.en_US
dc.description.sponsorshipDokuz Eylul University [KB.FEN.13]en_US
dc.description.sponsorshipDokuz Eylul University, Grant/Award Number: 2010.KB.FEN.13en_US
dc.identifier.doi10.1002/jccs.201900020
dc.identifier.endpage1396en_US
dc.identifier.issn0009-4536
dc.identifier.issn2192-6549
dc.identifier.issue10en_US
dc.identifier.scopus2-s2.0-85065639208en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage1389en_US
dc.identifier.urihttps://doi.org/10.1002/jccs.201900020
dc.identifier.urihttps://hdl.handle.net/11616/98795
dc.identifier.volume66en_US
dc.identifier.wosWOS:000491034300020en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofJournal of The Chinese Chemical Societyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectchloride hydrateen_US
dc.subjectcrystal structureen_US
dc.subjectFT-IR and NMRen_US
dc.subjectHirshfeld surface analysisen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectUV-Visen_US
dc.titleSynthesis, crystal structures, spectral FT-IR, NMR and UV-Vis investigations and Hirshfeld surface analysis of two new 2-hydroxyethyl-substituted N-heterocyclic carbene precursorsen_US
dc.typeArticleen_US

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