Palladium(II)-N-heterocyclic carbene complexes: synthesis, characterization and catalytic application

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dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorCekirdek, Suzan
dc.contributor.authorYasar, Sedat
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:39:42Z
dc.date.available2024-08-04T20:39:42Z
dc.date.issued2014
dc.departmentİnönü Üniversitesien_US
dc.description.abstractN-Heterocyclic carbenes (NHCs) are of great importance and are powerful ligands for transition metals. A new series of sterically hindered benzimidazole-based NHC ligands (LHX) (2a, 2b, 2c, 2d, 2e, 2f), silver-NHC complexes (3a, 3b, 3c, 3d, 3e, 3f) and palladium-NHC complexes (4a, 4b, 4c, 4d, 4e, 4f) have been synthesized and characterized using appropriate spectroscopic techniques. Studies have focused on the development of a more efficient catalytic system for the Suzuki coupling reaction of aryl chlorides. Catalytic performance of Pd-NHC complexes and in situ prepared Pd(OAc)(2)/LHX catalysts has been investigated for the Suzuki cross-coupling reaction under mild reaction conditions in aqueous N,N-dimethylformamide (DMF). These complexes smoothly catalyzed the Suzuki-Miyaura reactions of electron-rich and electron-poor aryl chlorides. Copyright (c) 2014 John Wiley & Sons, Ltd.en_US
dc.description.sponsorshipGaziosmanpasa University Research Fund [GOP. B.A.P:2013/44, 2011/51, 2011/105]en_US
dc.description.sponsorshipThis work was financially supported by Gaziosmanpasa University Research Fund (GOP. B.A.P:2013/44, 2011/51 and 2011/105).en_US
dc.identifier.doi10.1002/aoc.3143
dc.identifier.endpage431en_US
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-84901202221en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage423en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.3143
dc.identifier.urihttps://hdl.handle.net/11616/96455
dc.identifier.volume28en_US
dc.identifier.wosWOS:000336440900007en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSuzuki reactionen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectpalladium-NHCen_US
dc.subjectphenyl boronic aciden_US
dc.titlePalladium(II)-N-heterocyclic carbene complexes: synthesis, characterization and catalytic applicationen_US
dc.typeArticleen_US

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