Synthesis, Characterization and Crystal Structure of New 2-Morpholinoethyl-Substituted Bis-(NHC)Pd(II) Complexes and the Catalytic Activity in the Direct Arylation Reaction

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dc.authoridAygün, Muhittin/0000-0001-9670-9062
dc.authoridAygün, Muhittin/0000-0001-9670-9062
dc.authoridAktaş, Aydın/0000-0001-8496-6782
dc.authorwosidBarut Celepci, Duygu/M-6189-2017
dc.authorwosidAygün, Muhittin/P-3605-2019
dc.authorwosidGök, Yetkin/AAA-5669-2021
dc.authorwosidAygün, Muhittin/E-9590-2011
dc.authorwosidAktaş, Aydın/J-6194-2019
dc.contributor.authorSari, Yakup
dc.contributor.authorAktas, Aydin
dc.contributor.authorCelepci, Duygu Barut
dc.contributor.authorGok, Yetkin
dc.contributor.authorAygun, Muhittin
dc.date.accessioned2024-08-04T20:43:16Z
dc.date.available2024-08-04T20:43:16Z
dc.date.issued2017
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThis paper contains the synthesis of the new 2-morpholinoethyl substituted bis-(NHC)Pd(II) complexes and their catalytic activity in direct arylation reaction. The new bis-(NHC)Pd(II) complexes have been prepared from Ag(I)NHC complexes by using transmetallation method. The new bis-(NHC)Pd(II) complexes have been characterized by using H-1 NMR, C-13 NMR, FTIR spectroscopy and elemental analysis techniques. Molecular and crystal structure of the complex 1a and its ligand (N-benzylbenzimidazole) were obtained by single crystal X-ray diffraction method. The new bis-(NHC)Pd(II) complexes exhibit activity in the reaction after being examined as catalysts in the direct arylation (C-H activation) reaction. [GRAPHICS] .en_US
dc.description.sponsorshipUniversity Research Grant [2010.KB.FEN.13]en_US
dc.description.sponsorshipThe authors acknowledge Inonu University Scientific and Technology Center for the elemental analyses of the compounds and Dokuz Eylul University for the use of the Rigaku Oxford Xcalibur Eos Diffractometer (purchased under University Research Grant No: 2010.KB.FEN.13).en_US
dc.identifier.doi10.1007/s10562-017-2132-3
dc.identifier.endpage2351en_US
dc.identifier.issn1011-372X
dc.identifier.issn1572-879X
dc.identifier.issue9en_US
dc.identifier.scopus2-s2.0-85023771948en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage2340en_US
dc.identifier.urihttps://doi.org/10.1007/s10562-017-2132-3
dc.identifier.urihttps://hdl.handle.net/11616/97892
dc.identifier.volume147en_US
dc.identifier.wosWOS:000407719300011en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofCatalysis Lettersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-Heterocyclic carbenesen_US
dc.subjectBis-(NHC) Pd(II)en_US
dc.subjectSingle crystal X-ray diffractionen_US
dc.subjectDirect arylationen_US
dc.subjectButylfuranen_US
dc.subjectButylthiopheneen_US
dc.titleSynthesis, Characterization and Crystal Structure of New 2-Morpholinoethyl-Substituted Bis-(NHC)Pd(II) Complexes and the Catalytic Activity in the Direct Arylation Reactionen_US
dc.typeArticleen_US

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