Ruthenium(II) complexes with 2,6-pyridyl-diimine ligands
| dc.authorid | Cetinkaya, Bekir/0000-0002-4551-8650 | |
| dc.contributor.author | Çetinkaya, B | |
| dc.contributor.author | Çetinkaya, E | |
| dc.contributor.author | Brookhart, M | |
| dc.contributor.author | White, PS | |
| dc.date.accessioned | 2024-08-04T20:12:07Z | |
| dc.date.available | 2024-08-04T20:12:07Z | |
| dc.date.issued | 1999 | |
| dc.department | İnönü Üniversitesi | en_US |
| dc.description.abstract | Reaction of [RuCl2(p-cymene)](2) with the tridentate N-N'-N ligands, 2,6-pyridyl-diimines, led to substitution of p-cymene. The resulting complexes, believed to be coordinatively unsaturated, exhibit efficient activity for the epoxidation of cyclohexene in the presence of iodosobenzene (PhIO): the complexes formed initially take up donor molecules such as acetonitrile to achieve hexacoordination. The molecular structure for one of these, (acetonitrile){2,6-bis[1-(4-methoxyphenylimino)ethyl]pyridine}dichlororuthenium(II), 2, has been determined by X-ray diffraction. The immediate coordination sphere is a distorted octahedron with trans chloride atoms and a short Ru-N(py) (1.906 Angstrom) bond. (C) 1999 Elsevier Science B.V. All rights reserved. | en_US |
| dc.identifier.doi | 10.1016/S1381-1169(98)00285-4 | |
| dc.identifier.endpage | 112 | en_US |
| dc.identifier.issn | 1381-1169 | |
| dc.identifier.issue | 2 | en_US |
| dc.identifier.scopus | 2-s2.0-0033542359 | en_US |
| dc.identifier.scopusquality | N/A | en_US |
| dc.identifier.startpage | 101 | en_US |
| dc.identifier.uri | https://doi.org/10.1016/S1381-1169(98)00285-4 | |
| dc.identifier.uri | https://hdl.handle.net/11616/93203 | |
| dc.identifier.volume | 142 | en_US |
| dc.identifier.wos | WOS:000079815100001 | en_US |
| dc.identifier.wosquality | Q2 | en_US |
| dc.indekslendigikaynak | Web of Science | en_US |
| dc.indekslendigikaynak | Scopus | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | Elsevier Science Bv | en_US |
| dc.relation.ispartof | Journal of Molecular Catalysis A-Chemical | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | pyridine-2,6-diimines | en_US |
| dc.subject | ruthenium(II) complexes | en_US |
| dc.subject | epoxidation catalysts | en_US |
| dc.subject | epoxidation of cyclohexene | en_US |
| dc.subject | X-ray structure of Ru(II) | en_US |
| dc.title | Ruthenium(II) complexes with 2,6-pyridyl-diimine ligands | en_US |
| dc.type | Article | en_US |
