Architectures of zeolitic imidazolate framework derived Cu2Se/ZnSe@NPC and Cu1.95Se@NPC nanoparticles as anode materials for sodium-ion and lithium-ion batteries

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dc.contributor.authorBugday, Nesrin
dc.contributor.authorHuang, Jiangnan
dc.contributor.authorDeng, Wentao
dc.contributor.authorZou, Guoqiang
dc.contributor.authorHou, Hongshuai
dc.contributor.authorJi, Xiaobo
dc.contributor.authorYasar, Sedat
dc.date.accessioned2026-04-04T13:34:59Z
dc.date.available2026-04-04T13:34:59Z
dc.date.issued2025
dc.departmentİnönü Üniversitesi
dc.description.abstractTransition metal selenides (TMSes) face challenges such as low electronic conductivity, significant volume expansion, and particle agglomeration during charge and discharge processes, limiting their practical application in batteries. A promising solution involves integrating a carbon matrix into TMS-based anodes, which can enhance conductivity and mitigate volume stress. In this study, we synthesized novel Cu Se/ZnSe@NPC and Cu Se@NPC nanoparticles, embedded in a nitrogen-doped porous carbon (NPC) network using zeolitic imidazolate framework-11 (ZIF-11) as a template, for the first time as anode materials in lithium-ion (LIBs) and sodium-ion batteries (SIBs). The Cu Se/ZnSe@NPC and Cu Se@NPC nanoparticles demonstrate impressive initial capacities of 762 and 712 mAh g-1 at 0.1 A g-1, respectively, and deliver specific capacities of 401 and 358 mAh g-1 at 0.3 A g-1 for lithium-ion half-cell batteries. For sodium-ion half-cell batteries, these materials achievesatisfactory initial capacities of 455 and 349 mAh g-1 at 0.1 A g-1, and exhibit exceptional cycling stability with capacities of 223 and 204 mAh g-1 after 1000 cycles at 2 A g-1, respectively.
dc.description.sponsorshipScientific and Technological Research Council of Turkiye (TUBITAK) [122N559]; BAP Unit of Inonue University [FDK-2023-3311]; Department of Science Fellowships and Grant Programmes (TUBITAK, BIDEB) [2214-A]; Central South University, College of Chemistry and Chemical Engineering
dc.description.sponsorshipThis work was supported by the The Scientific and Technological Research Council of Turkiye (TUBITAK) with the project number 122N559, the BAP Unit of Inonue University with the project number FDK-2023-3311, and N. Bugday was supported by Department of Science Fellowships and Grant Programmes (TUBITAK, BIDEB, 2214-A) for studying in the Central South University, College of Chemistry and Chemical Engineering.
dc.identifier.doi10.1016/j.jpowsour.2025.236352
dc.identifier.issn0378-7753
dc.identifier.issn1873-2755
dc.identifier.orcid0000-0001-8201-4614
dc.identifier.orcid0000-0002-3882-035X
dc.identifier.orcid0000-0001-7285-2761
dc.identifier.scopus2-s2.0-85216303597
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.jpowsour.2025.236352
dc.identifier.urihttps://hdl.handle.net/11616/109514
dc.identifier.volume632
dc.identifier.wosWOS:001423748200001
dc.identifier.wosqualityQ1
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Power Sources
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250329
dc.subjectZIF-11
dc.subjectMetal selenide
dc.subjectLi-ion/Na-ion batteries
dc.subjectFull cell
dc.titleArchitectures of zeolitic imidazolate framework derived Cu2Se/ZnSe@NPC and Cu1.95Se@NPC nanoparticles as anode materials for sodium-ion and lithium-ion batteries
dc.typeArticle

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