Reduction hydrogenation of imines by in situ generated rhodium NHC complexes

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dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridkaraca, emine özge/0000-0003-2094-9742
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridDüşünceli, Serpil Demir/0000-0001-8765-4039
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidkaraca, emine özge/AAH-2535-2019
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidDüşünceli, Serpil Demir/AAA-7160-2021
dc.contributor.authorKaraca, Emine Ozge
dc.contributor.authorDusunceli, Serpil Demir
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:47:16Z
dc.date.available2024-08-04T20:47:16Z
dc.date.issued2020
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this paper we examined the catalytic activity of in situ prepared bidentate azolium salt/[RhCl(COD)](2) catalyst system in the transfer hydrogenation of imines with i-propanol to the corresponding amine. The first in situ transfer hydrogenation of imines to amines is described using [RhCl(COD)](2) with bidentate azolium ligands. New bidentate azolium salts (1a-c, 2a-c) as NHC precursors have been synthesized and characterized. The in situ prepared three-component bidentate azolium salts (LHX)/[RhCl(COD)](2) and t-BuOK catalyzes quantitatively the transfer hydrogenation of imines under mild reaction conditions in i-propanol. The results show that bidentate benzimidazolium salts were observed to be more active in reducing imines. Moreover, the method is simple and effective against various imines. (C) 2020 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK [TBAG (107T098)]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK [TBAG (107T098)].en_US
dc.identifier.doi10.1016/j.molstruc.2020.128351
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85084175638en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2020.128351
dc.identifier.urihttps://hdl.handle.net/11616/99269
dc.identifier.volume1216en_US
dc.identifier.wosWOS:000548598300021en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRhodiumen_US
dc.subjectBidentate azolium salten_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectImineen_US
dc.subjectTransfer hydrogenationen_US
dc.titleReduction hydrogenation of imines by in situ generated rhodium NHC complexesen_US
dc.typeArticleen_US

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