1,1?,3,3?-tetraalkyl-2,2?-biperimidinylidenes
| dc.authorid | Hokelek, Tuncer/0000-0002-8602-4382 | |
| dc.authorid | Cetinkaya, Bekir/0000-0002-4551-8650 | |
| dc.authorwosid | Hokelek, Tuncer/G-6068-2013 | |
| dc.authorwosid | Hokelek, Tuncer/JCE-0691-2023 | |
| dc.contributor.author | Alici, B | |
| dc.contributor.author | Hökelek, T | |
| dc.contributor.author | Çetinkaya, E | |
| dc.contributor.author | Çetinkaya, B | |
| dc.date.accessioned | 2024-08-04T20:13:14Z | |
| dc.date.available | 2024-08-04T20:13:14Z | |
| dc.date.issued | 2003 | |
| dc.department | İnönü Üniversitesi | en_US |
| dc.description.abstract | C-2 deprotonation of 1,3-dibutylperimidinium bromide (1a) with sodium hydride and a catalytic amount of potassium tert-butoxide in dry THF led to the formation of the exceptionally inert tetraaminoalkene 2a. In contrast, isostructural tetrakis(2-methoxyethyl)-tetraaminoalkene (2b) instantaneously reacted with O-2 to yield urea 3b, and silver nitrate was readily reduced with 2b to form a silver mirror. Compound 2a has been characterized by X-ray diffraction studies; the naphtho-pyrimidine skeleton imposes structural constraints and some rigidity to the C=C bonding. (C) 2003 Wiley Periodicals, Inc. | en_US |
| dc.identifier.doi | 10.1002/hc.10088 | |
| dc.identifier.endpage | 87 | en_US |
| dc.identifier.issn | 1042-7163 | |
| dc.identifier.issue | 1 | en_US |
| dc.identifier.scopus | 2-s2.0-0037277589 | en_US |
| dc.identifier.scopusquality | N/A | en_US |
| dc.identifier.startpage | 82 | en_US |
| dc.identifier.uri | https://doi.org/10.1002/hc.10088 | |
| dc.identifier.uri | https://hdl.handle.net/11616/93486 | |
| dc.identifier.volume | 14 | en_US |
| dc.identifier.wos | WOS:000180824700013 | en_US |
| dc.identifier.wosquality | Q2 | en_US |
| dc.indekslendigikaynak | Web of Science | en_US |
| dc.indekslendigikaynak | Scopus | en_US |
| dc.language.iso | en | en_US |
| dc.publisher | John Wiley & Sons Inc | en_US |
| dc.relation.ispartof | Heteroatom Chemistry | en_US |
| dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/closedAccess | en_US |
| dc.subject | Enetetramines | en_US |
| dc.subject | Catalysts | en_US |
| dc.subject | Complexes | en_US |
| dc.subject | Chemistry | en_US |
| dc.subject | Carbenes | en_US |
| dc.title | 1,1?,3,3?-tetraalkyl-2,2?-biperimidinylidenes | en_US |
| dc.type | Article | en_US |
