Resorcinarene-Functionalised Imidazolium Salts as Ligand Precursors for Palladium-Catalysed SuzukiMiyaura Cross-Couplings

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authorwosidTOUPET, Loic/N-7043-2014
dc.authorwosidŞAHİN, Neslihan/F-6402-2019
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorSahin, Neslihan
dc.contributor.authorSemeril, David
dc.contributor.authorBrenner, Eric
dc.contributor.authorMatt, Dominique
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorKaya, Cemal
dc.contributor.authorToupet, Loic
dc.date.accessioned2024-08-04T20:37:34Z
dc.date.available2024-08-04T20:37:34Z
dc.date.issued2013
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThree imidazolium salts based on a rigid resorcinarene platform (13) were synthesised and used as catalyst precursors in the SuzukiMiyaura cross-coupling of aryl halides with phenylboronic acid. In these pro-carbene ligands, the heterocyclic moiety has one N atom connected to a C2 atom of a resorcinolic ring, and the other is substituted by an alkyl group (R=n-propyl, iso-propyl, benzyl). The methinic C atoms of the macrocyclic core are all substituted by a pentyl group. The best catalytic performances were obtained by using an imidazolium/Pd ratio of 1:1. The catalytic systems displayed high activities, which increased in the order R=n-propyl(1)en_US
dc.description.sponsorshipscientific and technological research of Turkey (TUBITAK-BIDEB); International Research Fellowship Programmeen_US
dc.description.sponsorshipThe authors thank the scientific and technological research of Turkey (TUBITAK-BIDEB) and the International Research Fellowship Programme for the grant to N.S. Grateful acknowledgement is due to Johnson Matthey for a loan of palladium.en_US
dc.identifier.doi10.1002/cctc.201200716
dc.identifier.endpage1125en_US
dc.identifier.issn1867-3880
dc.identifier.issn1867-3899
dc.identifier.issue5en_US
dc.identifier.scopus2-s2.0-84877057982en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage1116en_US
dc.identifier.urihttps://doi.org/10.1002/cctc.201200716
dc.identifier.urihttps://hdl.handle.net/11616/96044
dc.identifier.volume5en_US
dc.identifier.wosWOS:000318240600013en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofChemcatchemen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectcavitandsen_US
dc.subjectcarbenesen_US
dc.subjectpalladiumen_US
dc.subjectnitrogen heterocyclesen_US
dc.subjectcross-couplingen_US
dc.titleResorcinarene-Functionalised Imidazolium Salts as Ligand Precursors for Palladium-Catalysed SuzukiMiyaura Cross-Couplingsen_US
dc.typeArticleen_US

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