Challenges and recent advancements in MXene-based high-capacity electrodes for future generation rechargeable batteries
Küçük Resim Yok
Tarih
2025
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
An innovative family of 2-dimensional transition metal carbides, carbonitrides, and nitride multilayered materials, identified as MXenes, has attracted significant interest since the discovery of Ti3C2 in 2011. MXenes exhibit a broad surface area and excellent electronic conductivity and can be hydrophilic, hydrophobic, or a combination of both. It also possesses physical robustness, flexibility, and chemical and thermal resilience. Surface terminations such as hydroxyl (OH-), oxygen (O-), or fluorine (F-) groups impart hydrophilic properties to the surfaces of materials. Due to its outstanding conductive properties, large specific surface area, excellent mechanical characteristics, and distinctive multilayered structure, MXenes have extensive applications in energy storage devices, absorption processes, catalysis, and other fields. MXenes and related composite materials have gained significant traction in rechargeable batteries. While oxides, sulfides, and various other materials offer high capacities, they are also plagued by poor cyclability, limited conductivity, and volumetric expansion during reaction processes. Consequently, utilizing MXene-based composites can enhance the electronic conductivity, storage capacity, and overall electrochemical efficiency while mitigating volumetric expansion during charge/ discharge cycles. This comprehensive review article delves into the manufacturing process, structure, and characteristics of MXenes. We also explore the energy storage capabilities of these materials in future-generation rechargeable batteries, associated applications, and prospects for future research.
Açıklama
Anahtar Kelimeler
MXene-based electrodes, Affecting Parameters, Properties of MXene, Bottom-Up Approach, Top-Down Approaches, Post-MXene Processing Techniques, Titanium-based MXenes, Vanadium-based MXenes, Niobium-based MXenes, Li-ion Batteries, Na-ion Batteries, Potassium-ion Batteries, Lithium-sulfur Batteries, Li-Metal Batteries, Multivalent Metal-ion batteries, Zn-ion Batteries, Magnesium-ion battery, Aluminum-ion battery
Kaynak
Journal of Energy Storage
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
132
