Well-defined PEPPSI-themed palladium-NHC complexes: synthesis, and catalytic application in the direct arylation of heteroarenes

Basit Öğe Kaydı
dc.authoridÖzdemir, Namık/0000-0003-3371-9874
dc.authoridKaloğlu, Murat/0000-0002-2770-5532
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridYILDIRIM GÜMÜŞHAN, İlkay/0000-0002-7423-5043
dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authorwosidÖzdemir, Namık/J-6434-2015
dc.authorwosidKaloğlu, Murat/AAA-3956-2021
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidYILDIRIM GÜMÜŞHAN, İlkay/JVN-8709-2024
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.contributor.authorKaloglu, Murat
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorYildirim, Ilkay
dc.contributor.authorOzdemir, Namik
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:46:59Z
dc.date.available2024-08-04T20:46:59Z
dc.date.issued2020
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this study, a series of benzimidazolium salts were synthesized as unsymmetrical N-heterocyclic carbene (NHC) precursors. Benzimidazolium salts were used for synthesis of the PEPPSI (pyridine enhanced precatalyst preparation stabilization and initiation)-themed, six new Pd-complexes with the general formula [PdX2(NHC)(pyridine)]. The structures of all compounds were characterized by various spectroscopic techniques such as H-1 NMR, C-13 NMR and FT-IR. The more detailed structural characterization of four of the complexes was determined by single-crystal X-ray diffraction study. The catalytic activities of all Pd-complexes were evaluated in the direct arylation of the 2-acetylfuran and 2-acetylthiophene with aryl bromides in the presence of 1 mol% catalyst loading.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TuBTAK [117R010]en_US
dc.description.sponsorshipThis study was supported by the Technological and Scientific Research Council of Turkey TuBTAK (project no. 117R010).en_US
dc.identifier.doi10.1002/aoc.5387
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-85076105596en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.5387
dc.identifier.urihttps://hdl.handle.net/11616/99093
dc.identifier.volume34en_US
dc.identifier.wosWOS:000500379900001en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectdirect arylationen_US
dc.subjectheteroareneen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectpalladiumen_US
dc.subjectPEPPSIen_US
dc.titleWell-defined PEPPSI-themed palladium-NHC complexes: synthesis, and catalytic application in the direct arylation of heteroarenesen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu