N-Propylphthalimide-substituted bis-(NHC)PdX2 complexes: synthesis, characterization and catalytic activity in direct arylation reactions

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dc.authoridAktaş, Aydın/0000-0001-8496-6782
dc.authorwosidGök, Yetkin/AAA-5669-2021
dc.authorwosidAktaş, Aydın/J-6194-2019
dc.contributor.authorErdogan, Hulya
dc.contributor.authorAktas, Aydin
dc.contributor.authorGok, Yetkin
dc.contributor.authorSari, Yakup
dc.date.accessioned2024-08-04T20:44:06Z
dc.date.available2024-08-04T20:44:06Z
dc.date.issued2018
dc.departmentİnönü Üniversitesien_US
dc.description.abstractPalladium-catalyzed direct arylation of heteroaromatics has become a popular method for producing carbon-carbon bonds via C-H bond activation. A wide diversity of heteroaromatics such as furan, thiophenes and thiazoles can be used for this reaction. This paper reports the synthesis of N-propylphthalimide-substituted bis-(NHC)PdX2 complexes (NHC = N-heterocyclic carbene), and their catalytic activity in direct arylation reactions. The complexes have been prepared from Ag(I)NHC precursors by transmetallation and characterized by spectroscopy and elemental analysis. The bis-(NHC)PdX2 complexes show excellent activity as catalysts in the direct arylation reactions of 2-n-butylfuran, 2-n-butylthiophene and 2-isopropylthiazole.en_US
dc.description.sponsorshipInonu University [IUBAP 2012/02]en_US
dc.description.sponsorshipThis work was financially supported by Inonu University Research Fund (IUBAP 2012/02) and the authors acknowledge Inonu University Scientific and Technology Center for the elemental analyses of the compounds.en_US
dc.identifier.doi10.1007/s11243-017-0190-4
dc.identifier.endpage37en_US
dc.identifier.issn0340-4285
dc.identifier.issn1572-901X
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-85033402332en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage31en_US
dc.identifier.urihttps://doi.org/10.1007/s11243-017-0190-4
dc.identifier.urihttps://hdl.handle.net/11616/98019
dc.identifier.volume43en_US
dc.identifier.wosWOS:000422664800004en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofTransition Metal Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectHeterocyclic Carbene Complexesen_US
dc.subjectC-H Bondsen_US
dc.subjectCross-Coupling Reactionsen_US
dc.subjectFunctionalizationen_US
dc.titleN-Propylphthalimide-substituted bis-(NHC)PdX2 complexes: synthesis, characterization and catalytic activity in direct arylation reactionsen_US
dc.typeArticleen_US

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