Synthesis of novel palladium(II) N-heterocyclic carbene complexes and their catalytic activities in the direct C5 arylation reactions

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dc.authorwosidGök, Yetkin/AAA-5669-2021
dc.contributor.authorYigit, Murat
dc.contributor.authorYigit, Beyhan
dc.contributor.authorGok, Yetkin
dc.date.accessioned2024-08-04T20:42:33Z
dc.date.available2024-08-04T20:42:33Z
dc.date.issued2016
dc.departmentİnönü Üniversitesien_US
dc.description.abstractNew palladium(II) N-heterocyclic carbene complexes have been easily obtained in good yields from the carbene transfer reaction of silver-NHC complexes with PdCl2(PhCN)(2) and characterized by elemental analysis, H-1 NMR and C-13 NMR spectroscopy. These complexes were used as catalysts in the direct C5 arylation of 2-n-butylfuran, 2-n-butylthiophene and 2-n-propylthiazole with various aryl bromides at 130 degrees C in N,N-dimethylacetamide (DMAc) for 1 h. The arylation reactions were regioselective, and in all cases, only the C5-arylated products were formed. The corresponding arylation products were obtained in moderate to good yields by using 0.5 mol% of palladium-NHC complexes. (C) 2016 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipAdiyaman University Research Fund [FEF-MAP/2015-0004]en_US
dc.description.sponsorshipWe thank the Adiyaman University Research Fund (FEF-MAP/2015-0004) for financial support of this work.en_US
dc.identifier.doi10.1016/j.ica.2016.07.055
dc.identifier.endpage28en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-84979998269en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage23en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2016.07.055
dc.identifier.urihttps://hdl.handle.net/11616/97449
dc.identifier.volume453en_US
dc.identifier.wosWOS:000387625500004en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectDirect arylationen_US
dc.subjectPalladium complexesen_US
dc.subjectBenzimidazoleen_US
dc.titleSynthesis of novel palladium(II) N-heterocyclic carbene complexes and their catalytic activities in the direct C5 arylation reactionsen_US
dc.typeArticleen_US

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