SYNTHESIS OF 1,3-DIALKYLPERHYDROBENZIMIDAZOLINIUM SALTS AND THEIR CATALYTIC PROPERTIES IN HECK REACTIONS
Küçük Resim Yok
Tarih
2013
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Pergamon-Elsevier Science Ltd
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Novel eight 1,3-dialkylperhydrobenzimidazolinium chloride salts 3a-h were prepared as precursors of N-heterocyclic carbenes by reacting N,N'-dialkylcyclohexanediamine, triethyl orthoformate and ammonium chloride. The salts were characterized spectroscopically and the complexes formed in situ from Pd(OAc)(2) and 3 have been tested as catalysts in homogenous Heck coupling reactions.
Açıklama
Anahtar Kelimeler
Heck Reaction, Imidazolinium Salt, N-Heterocyclic Carbene, Palladium Catalyst
Kaynak
Heterocycles
WoS Q Değeri
Q3
Scopus Q Değeri
Q4
Cilt
87
Sayı
4
